MadSci Network: Physics |
This question has answers at several different levels. The first, and simplest answer runs as follows: If we are thinking of a stationary, isolated atom of hydrogen-1, there are only two particles present - a proton and an electron. The proton is about 2000 times as massive as the electron. We normally think of the proton as infinitely massive by comparison with the electron. But if we want to be more realistic, we must remember that both proton and electron will move. But the centre-of-mass of the two particle system will remain stationary. Whenever the electron moves anywhere, the proton will move 1/2000 of the distance in the opposite direction. This behaviour in classical mechanics continues much the same way in quantum mechanics. Motions of the electron and proton are exactly correlated. The electron and proton ***share*** the same wavefunction. If it is the 1s wavefunction, then at the same time as it spreads the electron over a sphere of about 600 picometres radius, it will spread the proton over a corresponding sphere 2000 times smaller - about 300 femtometres radius. There are two other senses in which we think about the wavefunctions of an atomic nucleus, or of the particles in an atomic nucleus. The first is the concern of particle physicists, who think about the way the protons and neutrons move around past one another within the region of a multi-particle atomic nucleus. In this sense, a proton in a multi-particle nucleus can have its own wavefunction which is very similar to that of an electron in an atomic orbital, but on a much smaller scale. The second sense is used mainly by chemists, who need to consider the motions of the two atoms at the ends of a chemical bond in a molecule, and how they vibrate, in a quantum mechanical sense. These vibrational wavefunctions are usually ascribed to the atomic nucleus as a whole, and are usually much more complicated in shape than electron wavefunctions because the geometry of any molecule is much less symmetric than the spherical geometry of an atom. John.