MadSci Network: Physics |
Ryan, I'll try to simplify the complex subject of rheology, that is, the study of moving fluids. Newtonian rheology is one in which the resistance to deformation [flow]is directly proportional to the force of that deformation [shear]. Water is the usual example: if you stir water very slowly, you don't feel much resistance against the spoon. If you stir faster, you'll notice more resistance against the spoon. If you could measure both forces with a machine called a viscometer [from 'viscosity' a word used to describe the force of the resistance to flow] you would see that the viscosity of water is directly proportional to the force applied trying to make it flow; The plot of viscosity versus stirring force would be a straight line. Any flow behavior that does not result in a straight line plot is called non- Newtonian. Some solutions and fluids resist less the faster they are stirred; this is called thixotropic [or shear thinning] rheology. Latex wall paint is a good example of this. It looks really thick in the pail, but glides onto the wall very easily because the motion of the brush is the same thing as stirring, so it 'thins out' during application but goes back to its thick state when the force is removed. This is why it doesn't run down the wall after you paint it. The plot of viscosity versus stirring pressure is a curve heading downward. Your water-cornstarch slurry is not a colloid, but a dispersion of a solid [starch] in a fluid [water]. Colloids are similar, but much smaller and is beyond todays question. You've already observed that at a certain starch to water ratio that the dispersion flows like something slimy when you stir it very slowly but that when you stir real hard [or punch it] it hardens up. This non-Newtonian rheology is called dilatent [or shear thickening]. Another example of this is the wet sand at the edge of a beach that flows through your hands easily but hardens when you take a step on it. A plot of this dilatent viscosity versus force curves upward, i.e. a little more force will give you a lot more viscosity. There are at least three or four other sub-categories of rheology, but I hope this helps to explain your observations. Ken
Try the links in the MadSci Library for more information on Physics.