MadSci Network: Chemistry |
Entropy, the thermodynamic state function that drives reactions to equilibrium, was defined by Rudolf Clausius in the early 1860's. He was also responsible for chosing the letter S to represent entropy in thermodynamic equations. The consensus, as I have found, in the thermodynamic community is that Clausius' choice of S was purely arbitrary. This leads me to suspect that S was chosen because it lies between Q (Heat) and T (Temperature) - the variables which define entropy - and R (the ideal gas constant) was already taken. That way the equation for entropy and its components would have (nearly) consecutive letters:
dQ dS = --- T
This is still a guess, since Clausius died without explaining his choice, but it fits better than most other explanations I have heard.
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