MadSci Network: Chemistry |
Dear friend, Before answering your question, I would like to give you an introduction about fuels and organic chemistry in general and then we will shift to your question. I hope you know from chemistry that organic compounds, or hydrocarbons are divided into two main groups: 1-Aliphatic compounds: under which there are three sub groups: Alkanes, Alkenes and Alkynes. These compounds are open chain compounds . 2-Aromatic compounds: These are characterized by the famous benzene ring. (honey comb like ring) You mentioned ethane in your question. I guess you meant it to be the fuel used in your car. However this is not true. The fuel you use in the car is by mistake called benzene. Its actual name is gasoline. Surprisingly, this gasoline is composed of different (a variety of) long open chain aliphatic compounds, and no closed (aromatic compounds), despite its commercial name (benzene) gives that false idea. There are some points one must consider when it is about to select a fuel: 1-Does the fuel have a high calorific value? 2-Is it poisonous ? 3-On combustion, what are the waste substances produced? 4-Does it contain impurities or not? If yes, then is it expensive to purify it? 5-After all of this, will the fuel remain with a reasonable price or not? You are stating two different fuels to use; hydrazine and ethane. You are asking why do they use hydrazine in stead of ethane. Let me go though the above 5 points one by one. You know that oxidation or combustion of the fuel is the fast oxidation of the fuel accompanies by liberation of energy. The petroleum oil, referred to as gasoline produced a calorific value of: 48 k Joule/gram. To be specific, the car fuel is called ISO-octane: [(CH{3})3CCH{2}CH(CH{3}){2}]. Its calorific value is 47.8 k .joule/gram. ISO-octane is an excellent smooth- burning automotive fuel; it is given an octane number 100. On the other side, there is heptane [CH{3}(CH{2}){5}CH{3}]. It burns unevenly, and causes the motor to knock, and given octane number of 0. Thus by putting ratios of both chemicals, you form the fuel of certain octane number. Now what about ethane? Ethane (C2H6) is a gas at room temperature. It has a melting point at -183 C, and boiling point at -89 C. Its density is 0.546 Kg/m^3 at -89 C. I tried to find the heat of combustion of it, however I was not able to find it. However, we can agree on a close compound to it. Heat of oxidation of methane (CH4) is 850 kJ/mole. Let us shift to Hydrazine (N2H4). Hydrazine has a heat of combustion of 622.2 kJ/mole. Hence, arises a great question mark. Why do the folks of NASA put in space shuttle Columbia that gas even if it has less calorific value. The point is that hydrazine is NOT their fuel!! Their fuel is methyl-hydrazine ( CH3-NH=NH2) and hydrazine as well . This gas (methyl-hydrazine) burns in air generating enormous quantities of heat; hence it is more beneficial to use in the space shuttle. The second point that adds to why they use this compound as their fuel is that because this compound is a liquid compound and not a gas one like ethane. You know to keep a gas, of such a low density, you need to keep it under large pressure in order to keep large amounts of it. (I guess you know that in order to keep in a container large amounts of gas mass, you should keep it under large pressure. Hence, in space this is not easy) The third point that adds to hydrazine is its by-products of its combustion. It gives water vapor and Nitrogen. The fourth point that adds to hydrazine and its compounds is that it does not require ignition; when the hydrazine coming from its chamber meets the oxidizer at the combustion chamber, they ignite directly. On the other hand, ethane requires this ignition, and this ignition may create a lot of problems. That’ all for now. Thanks for the great question. References: = = = = = = Denial, M.J.. Investigating Chemistry. Heinemann Educational Books. Great Britain 1982. Petrucci, Ralph and Harwood, William. General Chemistry: Principles and Modern Applications. Prentice Hall International, USA. 1997 Encyclopaedia Encarta. Microsoft Corporation 1997. Moataz Attallah The American University in Cairo-Egypt Email:mizoa@aucegypt.edu Undergraduate Mechanical Engineering Student ======================================================= These are a group of Articles from Microsoft Encyclopaedia Encarta. I hope you will find them helpful 1-Hydrazine, colorless, oily liquid (H4N2), a powerful reducing agent, or electron donor. Derivatives of hydrazine are used (with strong oxidants, such as nitric acid) as rocket fuels, as corrosion inhibitors in boilers, in the synthesis of pharmaceuticals and agricultural chemicals, and in the rubber and plastic industries. Hydrazine is produced either by the reaction of chloramine (NH2Cl) with ammonia or by the reaction of sodium hypochlorite with urea. In both processes, gelatin or glue is used to prevent decomposition of hydrazine by unreacted oxidants. Hydrazine melts at 2° C (35.6° F) and boils at 113.5° C (236.3° F). ======================================================= 2-Liquid Propellants Although most of the scientists who pioneered in the field of liquid-propellant rockets used gasoline as a propellant, ethyl alcohol or refined kerosene has since been widely used. Ethyl alcohol, the fuel in such weapons as the V-2, Viking, and Redstone rockets, is burned with liquid oxygen, which, however, has the drawback of a boiling point so low that evaporation losses are considerable. The search for a substitute for liquid oxygen has led, partly by accident, to another class of liquid fuels, known as the hypergols, and consisting usually of nitric acid as the oxidizer and either aniline or a hydrazine as the fuel. A hypergolic propellant does not require ignition, because the fuel and the oxidizer ignite spontaneously when brought together. The hydrazine called unsymmetrical dimethylhydrazine is particularly good at providing spontaneous ignition. Liquid hydrogen is theoretically the most efficient fuel, but it is quite difficult and dangerous to handle. The problems of using liquid hydrogen, however, were successfully overcome by U.S. rocket engineers in the Centaur and Saturn 5 space launch vehicles and in the Space Transportation System, or Space Shuttle. ======================================================== 3-Liquid and Gaseous Fuels Common liquid fuels are fuel oils, gasoline, and naphthas derived from petroleum, and, to a lesser extent, coal tar, alcohol, and benzol obtained from coke manufacture. In stationary furnaces, less volatile fuel oils are sprayed through nozzles, with or without air or steam, into the combustion chamber. In an internal-combustion engine, volatile fuels such as gasoline or a gasoline and alcohol mixture (gasohol) are evaporated and the mixture admitted into the engine cylinder, where combustion is initiated by a spark. In these fuels, from 16 to 23 kg of air are required for complete combustion of 1 kg of fuel. In diesel engines the fuel is injected as an atomized spray into the combustion chamber, where the temperature rise associated with the high compression ratio of diesel engines is sufficient to cause ignition. Gaseous fuels such as natural gas, refinery gas, and manufactured gases such as producer gas are usually mixed with air before combustion to supply a maximum amount of oxygen to the fuel. The fuel-air mixture then issues from the burner ports at a velocity greater than the velocity of flame propagation to prevent flame flashback into the burner, but not so great a velocity as to blow the flame off the burner. If not premixed with air, these fuels usually burn with smoky, relatively cool flames. Natural gas burned with air can produce flame temperatures in excess of 1930° C (3500° F). Rockets for space exploration may use liquid fuels such as kerosene and hydrazine, and carry an oxidizer such as liquid oxygen, nitric acid, or hydrogen peroxide. ======================================================= Fuel, substance that reacts chemically with another to produce heat, or that produces heat by nuclear processes. The term fuel is generally limited to those substances that burn readily in air or oxygen, emitting large quantities of heat. Fuels are used for heating, for the production of steam for heating and power purposes, for powering internal-combustion engines (see Internal- Combustion Engine), and for a direct source of power in jet and rocket propulsion. In cases where a fuel must supply its own oxygen, as in many rockets and torpedoes, an oxidizing agent such as hydrogen peroxide or nitric acid is added to the fuel mixture (see Jet Propulsion; Rocket). Chemical reactions in the combustion of all ordinary fuels involve the combination of oxygen with any carbon, hydrogen, or sulfur present in the fuels. The end products are carbon dioxide, water, and sulfur dioxide. Other substances present in fuels do not contribute to the combustion but either are driven off in the form of vapor or remain after combustion in the form of ash. ======================================================== Fuel efficiency or heating value of a fuel is usually measured in terms of the number of Btu (see British Thermal Unit) that are produced when a given amount of the fuel is burned under standard conditions. Heating values for solid and liquid fuels are stated in terms of Btu per lb, and values for gases in Btu per cu ft. A distinction is sometimes made between higher heating value, the entire heat evolved during combustion, and lower heating value, the net heat evolved, with allowance for the heat lost in the vaporization of the water produced by combustion. Approximate higher heating values of common fuels are: Solid fuels (Btu per lb): coal 12,000 to 15,000; lignite 6000 to 7400; coke 12,400; dry wood 8500. Liquid fuels: alcohol 11,000; fuel oil 19,000; gasoline 20,750; kerosene 19,800. Gaseous fuels (Btu per cu ft): acetylene 1480; blast-furnace gas 93; carbon monoxide 317; coke-oven gas or coal gas about 600; hydrogen 319; natural gas 1050 to 2220; oil gas 516; producer gas 136. See separate articles on most of these fuel
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