MadSci Network: Science History |
Jane, Before I give you the answer, let me tell you how I found it. First, I looked in one of my old Chemistry textbooks where heat is discussed. Generally, there are references at the end of the Chapter for further reading on the subject. Then I looked up specific books on the electronic card catalog system for U. Penn's library. In the process, I found a better source for historical sorts of questions. If you just look under Physical Sciences or Thermodynamics (or any other broad subject), there are generally more specific subheadings you can sort through. In this case I looked up "Thermodynamics-- History" and found this: Cardwell, Donald, S. L. "From Watt to Clausius; the rise of thermodynamics in the early industrial age" Ithaca, N.Y., Cornell University Press [1971] Call Number: TJ265.C33 The point of going to this source is to find the original reference where "q" was used for heat, or at least a historical discussion of its introduction. It turns at the Cardwell book didn't give us the answer, but did reference the original work: Lavoisier, Antoine L., & Laplace, Pierre S. "Memoir on heat" ("Memoir sur la Chaleur") English translation: New York; N. Watson Academic Publications, 1982 (originally published in French, 1780) QC253.L313 It is a groundbreaking work, so most BIG libraries should have a copy in their Special Collections section. So, I went and looked at the original. Here's what Lavoisier and Laplace had in mind. They were trying to describe in a quantitative way what happens when you mix two substances at different temperatures. Their original experiments involved heating up different materials (metals, oils, all kinds of things) and then mixing it into a bucket of water at a different temperature. Warm Body: m = the mass of body 1 q = the quantity of heat which can raise the temperature of the body by one degree. a = the reading of the thermometer Cool Body (usually water in their experiments): m' = the mass of body 2 q' = the quantity of heat which can raise the temperature of body 2 by one degree. a' = temperature of body 2 Finally, b was defined as the end temperature after mixing the two materials together. They came up with the relations: Heat lost by body 1 = mq(a-b) mq(a-b) = m'q'(b-a') (q/q') = [m'(b-a)] / [m(a-b)] They didn't talk about heat as a physical picture, just as a "quantity" So, q stands for quantity, the quantity of heat which can raise the temperature of the body by one degree. (In French, if you want to impress your teacher, "C'est la quantite' q de chaleur qui peut e'lever d'un degre' la temperature d'une liver de cette quantite' de chaleur perdue.") I hope that covers it. Sincerely, Dr. Jim Kranz
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