MadSci Network: Chemistry
Query:

Re: When using chemical symbols, how is diamond differentiated from graphite?

Date: Wed Apr 14 07:45:28 1999
Posted By: Dan Berger, Faculty Chemistry/Science, Bluffton College
Area of science: Chemistry
ID: 924016161.Ch
Message:

When using chemical symbols, how is diamond differentiated from graphite?

I know that both diamond and graphite are allotropes of carbon, but all I can find is information on the difference in structure.


That's because in chemistry we don't always care about the allotrope being dealt with (as opposed to laboratory practice, or cost accounting - then we care very much indeed!)

Normally, phase differences or allotropic differences are represented by subscript words or abbreviations in parentheses. For example, when you mix a solution of barium nitrate with a solution of copper sulfate, you obtain a precipitate of barium sulfate. This is represented thus:

Ba(NO3)2(aq) + CuSO4(aq) ® Cu(NO3)2(aq) + BaSO4(s)

In this case, (aq) means a species in aqueous solution and (s) means a solid (or precipitated, sometimes represented by "ppt") material.

In the same way, if you wanted to represent diamond or graphite specifically you could write either C(diamond) or C(graphite).

There are special cases in which allotropes have different molecular formulae. For example, ozone (O3) and molecular oxygen (O2) are allotropes; so are white phosphorus (P4) and polymeric red phosphorus (Pn). For carbon, there are various molecular fullerene allotropes such as C60 and C70. In such cases, giving the correct molecular formula is sufficient.

  Dan Berger
  Bluffton College
  http://cs.bluffton.edu/ ~berger


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