MadSci Network: Chemistry
Query:

Re: Why are elements 104-109 on ref. table if wedon't know anything about them?

Date: Fri May 21 09:15:23 1999
Posted By: Dan Berger, Faculty Chemistry/Science, Bluffton College
Area of science: Chemistry
ID: 927074780.Ch
Message:

Why are elements 104-109 on ref. table if we don't know anything about them?

I don't understand why they are on there if we don't even know what they are and we don't even use them for anything. What are they anyway? Do they have specific names,like Ag is silver? Who "found" these elements anyway and how did they discover them? Did they just stumble over them when trying to figure out something else or were they actually focused on looking for that specific thing?


Mary,

You are taking an instrumental view of science, insisting that what we do must have a "practical" application. That's no more true of science than it is of any other fine art (like painting or literature). There is "applied science," just as there are people who paint portraits and draw engineering diagrams, and people who write user manuals and textbooks, but that's not what science is about. For more, please read another of my answers.

Elements 104-109, and 110-112, and 87, and 85, and 96-103 (all of which are so unstable that they are essentially "useless") are on the periodic table because the periodic table is, first, a listing of all known elements. All of the elements of atomic number 93 and above are artificially made (not to mention element 43, which is used in medical research as a tracer, and element 85), because uranium is the heaviest element found in quantity in the Earth's crust (the other radioactive element found in quantity is thorium, 90). All higher elements (including plutonium, used as a nuclear fuel and as a thermoelectric power source for deep space probes, and americium, used in smoke detectors) are too unstable to have survived since the formation of the Earth. And elements 84, 86-89 and 91 are only found in nature because they are products of the slow decay of thorium or uranium. Most of these are too unstable to have technological uses; element 87 has never been isolated in visible quantities.

Atomic
number
Symbol Name
104 Rf rutherfordium
105 Db dubnium
106 Sg seaborgium
107 Bh bohrium
108 Hs hassium
109 Mt meitnerium
Elements 104-109 all belong to the transition metals, for which the outermost d subshell is the most important for their chemistry. Because the periodic table is based on a sort by chemical and physical properties (most of which, in turn, depend on the valence electrons), we can make good guesses as to the physical and chemical properties of these elements. When tested, these predictions have largely held up; for example, two or three compounds of element 106 have been made and its chemical behavior seems similar to that of tungsten (the element immediately above it). See another of my answers.

All these elements, as well as elements 110, 111, 112 and 114, were synthesized by nuclear physicists by the technique of heavy-ion bombardment. In this techique, two fairly heavy nucleii (like calcium and radium) are smashed together to form a new nucleus. None of those so far discovered are very stable, but there is a method to the madness.

The generally-accepted model of how protons and neutrons "stack" themselves in atomic nucleii is called the shell model. According to this model, a nucleus with 114 protons or 184 neutrons ought to be especially stable; the experiments in which new elements are made are, then, designed to test our understanding of the structure of the atomic nucleus.

Nuclide half-life
(seconds)
289Uuq 30
285Uub  0.0003
272Uuu  0.002
271Uun  0.009
268Mt  0.07
263Hs  1.0
262Bh  0.1
266Sg 20
258Db  4.2
257Rf  4.7
And, in fact, a single atom of element 114 (289Uuq, with 175 neutrons) was recently synthesized and took over 30 seconds to decay (whereas the most stable isotope of rutherfordium, 257Rf, takes less than 5 seconds). The long half-life of 289Uuq is especially impressive if we remember that odd numbers spell instability, and 289Uuq has an odd number of neutrons.

For more information on the elements and their most common uses, consult WebElements.

  Dan Berger
  Bluffton College
  http://cs.bluffton.edu/~berger


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