MadSci Network: Chemistry |
I trust that this is a general query, and not related to any legal proceedings. I do not claim special expertise in this area. You must look elsewhere for an authoritative answer. By "chlorine pellets", I imagine you are meaning a form of swimming pool chlorine or bleaching powder. That is, calcium hypochlorite Ca(OCl)2 or sodium hypochlorite NaOCl, possibly mixed with calcium or sodium chloride respectively. The ammonia from diapers is clearly in an environment where there will be plenty of dampness present, and almost certainly significant amounts of urea, and other organic nitrogen-containing compounds related to ammonia. Then, if the worry is about a toxic gas forming, it does not have to be the result of a major and efficient reaction. Small amounts of reaction could be enough to cause trouble if the product were sufficiently toxic. Clearly the situation that might apply in a mixed garbage disposal environment is about as far from the controlled environment where the chemist likes to study reactions as you can get. Having got past all of that hedging and those caveats, I think the simplest and most likely toxic gas that you might be dealing with in this situation is monochloramine -- NH2Cl. It can form in a reaction that amounts to NH3 (ammonia) + Cl2 (chlorine gas) -> NH2Cl (monochloramine) + HCl or NH3 + OCl-(hypochlorite ion) -> NH2Cl + OH-(hydroxyl ion) (See, for Example, S Zumdahl, Chemistry, 4th Edition, p. 667). It is not a very efficient reaction, and the mechanism is probably much more complicated. There are certainly many other possibilities, including organic chloramines R-NHCl, where R might be one of several sorts of carbon chains.
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