MadSci Network: Chemistry |
Alexis, You have a great question. After reading you question, I thought that the results you saw were incorrect, but after thinking about it more,I am sure what you saw when the temperature rose IS what you should see. If you think about what is going on, the water vapor (steam) is saturating the air above the boiling water. Eventually you are going to get so much water into the air to the point where water does not want to boil. That is you are bringing the vapor pressure of the boiling water and the steam to where they are almost the same. Essentially, you have overcome the vapor pressure of the water in solution by having a saturated air "solution" above it. So the water will begin to cool because it is slightly lower than the boiling point. You will still see some boiling becasue there is an equilibrium between molecules of steam condensing to water and the water reboiling to replace the condensed ones. When you cool the steam it converts to water, this conversion lowers the vapor pressure on the saturated air above the water. And when that steam is removed, the water will heat up to boiling again to replace those molecules of water you condensed. I sure hope this makes sense. It seems confusing but if you will remember that you are removing molecules of water in the vapor state which allows room for more water molecules, the water will boil. If the steam is not allowed to be released you can actually stop the water from boiling. You can also get water to boil at room temperature if you lower the vapor pressure above the surface. Good luck! Carlin Gregory, William-Texas Gas
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