MadSci Network: Chemistry |
Hi Jeremy,
this is simply a matter of definition - (the graphics are extracted from http://www.fed.cuhk.edu.hk/~johnson/teaching/biology_lesson/molec
ules/semnet/).
The definition of a solid is ,
the definition of a liquid is ,
and (to make it complete) the definition of a gas is
.
You see that as soon as you have freely movable molecules, you have the
liquid state. Of course it's not that simple if you think further - you
can't always say "That's a liquid!" and so on, sometimes you have
properties of one state compined with properties of another state.
But in order to define the state of a substance you have to exclude
interfaces. In your case you have a lot of those ice/gas (or air)
interfaces, and you can't apply the concept of solid/liquid/gaseous state -
you can apply it for the ice clusters in this case, an there it is a solid.
You need a ->homogeneous<- phase to apply the concept (i.e. physical
properties are the same everywhere), otherwise you could ask "What's the
state of matter of the earth?" - but you can't, because it's not
homogeneous :) !
Bye,
Andreas
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