MadSci Network: Chemistry
Query:

Re: Microwaves plastics, and ceramics

Date: Mon May 22 12:19:43 2000
Posted By: Adrian Popa, Directors Office, Hughes Research Laboratories
Area of science: Chemistry
ID: 957696741.Ch
Message:


Greetings:

Although the total electrical charge in molecules is neutral, the positive 
and negative charges do not occur at the same location within the molecule. 
The amount of separation between the positive and negative charges is called 
the dipole moment of the molecule. Some molecules have small dipole moments 
and some molecules such as water have large dipole moments.  The microwave 
energy passing through a material placed in a microwave oven rapidly 
alternates between positive and negative voltage 2450 million times per 
second (2450 Megahertz). The alternating electric field causes the charges 
of the dipoles to try to align the molecules with the microwave field, plus 
to minus and minus to plus. This causes the molecules to rapidly rotate 
generating heat by friction like forces.   

There are two reasons why plastics heat more then ceramics in a microwave 
oven. First, plastics can trap water within the material during the 
manufacturing process. The very high temperatures required to manufacture 
ceramics drives all the water out of the material. The trapped and possible 
absorbed water molecules cause the plastics to heat more than ceramics when 
exposed to a microwave field.

The second reason that some plastics heat more than others in microwave 
fields is that plastics are formed from long changed hydrocarbon molecules 
that have there own dipole moments which can also cause heating of the 
plastic. Some ceramic glazes used for coloring also can also cause extra 
dipole heating in ceramics; these ceramics are usually not suitable for 
microwave cooking purposes.

You can find more detail with animation of the microwave cooking process on 
the following web site:
 http://
www.gallawa.com/microtech/howcook.html

Best regards, Your Mad Scientist
Adrian Popa




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