MadSci Network: Chemistry |
Thanks for your question. You seem to be trying experiments at home, which is great. It's how most of the most important discoveries were made! But I'm afraid what you have tried won't work - salt solution contains sodium ions and chloride ions and it has produced all kinds of reactions with your metals. To plate a metal you need an electrolyte (the solution) which contains a compound of the metal that you want to plate with - the metal ions in the compound will migrate to the cathode and be reduced. You also need an anode (the positive electrode) made of the same metal - this is oxidised into solution to replace the metal ions being removed at the cathode. The cathode (negative)is the metal object you want to be plated. For example to plate with COPPER you need a COPPER anode, COPPER SULPHATE solution and then the cathode is steel (or whatever you want to plate)- it must be very clean. You cannot easily plate something with any reactive metal. Zinc is a reactive metal and if you use an aqueous (water) solution then you'll get hydrogen produced at the cathode from the water, not zinc. You would have to use a molten zinc compound as the electrolyte (very hot and dangerous). Things are galvanised (or coated in zinc) using molten zinc and simply dipping the metal object into the liquid zinc. Clearly this is very hot and must not be done at home! I hope that explains things. Kevin
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