MadSci Network: Physics
Query:

Re: Can a Van de Graaff be used to convert uranium-238 into plutonium-239?

Date: Wed Sep 20 14:56:35 2000
Posted By: Scott Kniffin, , Nuclear Engineer, Unisys Corporation
Area of science: Physics
ID: 968790064.Ph
Message:

Hi Steve, 

The answer is sort of yes, sort of no.  You are correct in that neutrons 
are necessary for the production of Pu-239 from U-238, however, the 
neutrons themselves are not accelerated.  In order to get free neutrons, 
you generally need to take an H- ion (yes Hydrogen with an extra electron) 
and accelerate it into a high Z target, usually tungsten or some other 
heavy metal and through this process (called spallation) you get 
semi-directionally dependent neutrons out of the metal target.  There is a 
new facility being built that will use liquid Mercury for the target.  (See 
the web links below.)  

The functional problem with using a Van de Graaff, is that generally they 
don't have sufficient acceleration capability to produce a neutron that 
will be absorbed by the U-238.  There are some that do, it's just that they 
are put to better use for different things.  A cyclotron or linear 
accelerator would be the device of preference here.  If you don't care what 
the neutron spectrum looks like and/or want less than 10MeV neutrons, a 
fabulous source of neutrons would be a nuclear reactor.  Numerous research 
reactors exist in the US and abroad that fill this role in particle 
research.  

On to Pu production.  In order for U-238 to become Pu-239 it has to absorb 
a neutron and then undergo a beta decay (some gamma rays may be produced 
as well).  All isotopes of all elements have what is called a neutron cross 
section.  This is essentially the probability of an incident neutron being 
absorbed by the target nucleus and is neutron energy dependent.  The 
individual unit of cross section is the barn and it is 1x10E-24cm^2.  For 
most isotopes of most elements, the cross section is very small; well under 
one barn for most neutron energies.  However, some have a high enough cross 
section to soak up a neutron.  What happens next depends on the isotope.  
Some fission, some eject an alpha particle, some emitt gamma rays, some do 
other things not related the the topic right now, and some are capable of 
doing several of the above (but not more than one at a time).  In the case 
of U-238 it might fission, but that cross section is ~5microbarns; it might 
eject an alpha particle, but that cross section is ~1microbarn.  The most 
probable interaction is that it will give off a gamma ray after neutron 
absorbtion (becomming U-239 with a half-life of 23.5 minutes after which it 
will beta decay into Pu-239).  The cross section for this case ranges from 
about 2.7 to 277 barns depending on the neutron energy.  In this rare case, 
as the neutron energy goes up, so does the cross section.  Thus higher 
energy neutrons are prefered.  For an excellent example of how to make Pu, 
look up fast breeder reactors (US nuclear weapons program).  

You also asked about heat.  In a nuclear reactor, obviously, very hot 
(>300F) for a commercial power reactor, and rather cool for a research 
reactor (<200F generally).  If you use an accelerator, it depends on what 
mode you operate.  If the accelerator is pulsed and the target has proper 
cooling, the heat build up will generally be fairly small (<100F) as you 
don't want to damage the target that makes the neutrons.  If the beam is 
steady state, you can eaisly melt a metal target in a very short span of 
time with or without cooling (this is what tends to make VdG's a poor 
choice).  

Lastly, hazardous or radioactive waste.  The answer is that very little is 
produced, however, anything subjected to neutrons will absorb a certain 
fraction of them and become radioactive, even if only for an instant.  In 
the case of some things, they were radioactive to begin with and are merely 
something different that's also radioactive.  When sheilding for neutrons, 
you generally want to pick an isotope that wants to absorb a neutron and 
will rapidly decay into something nonradioactive.  Boron-10 is an excelent 
example.  It gladly absorbs a neutron (cross section of over 3800 barns) 
becomming B-11 and spontaneously alpa decays (an alpha particle you will 
remember is merely a helium nucleus witout electrons) into Li-7 which is 
stable.  There are many other examples, but that is a nuclear physics 
lesson for another day. 

Please check out the selection of websites below or just type in the words 
-neutron source- in Yahoo and go to the web page matches (the first few 
pages will have what you want).  

Good hunting!  

Scott Kniffin
Senior Engineer, Orbital Sciences Corporation
NASA Goddard Space Flight Center
Office of Systems Safety and Mission Assurance
Radiation Effects and Analysis Group, Code 562
 http://www.sns.gov/aboutsns/source.htm
 http://www.isis.rl.ac.uk/
 http://www.pns.anl.gov/





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