MadSci Network: Chemistry |
You can’t actually IDENTIFY an acid by titration. You need to carry out a systematic series of analytical tests first. The first thing to ascertain is whether it is an organic or mineral acid. If it is a mineral acid, then carry out the usual sulphate, nitrate tests etc. If it is organic, assuming you have access to the pure acid as solid or liquid, you can make up a volumetric solution using a known mass (e.g. 1g in 100ml). Next carry out a titration using standardised NaOH – you may have to make an assumption that, being organic, it is a weak acid and use phenolphthalein as indicator. It will also be pot luck if you get a reasonable titre depending on the concentration of NaOH you use. From the titre of NaOH calculate the possible molarity (concentration of the acid solution in moles per litre) assuming it to be monoprotic (HA - this is most likely) or diprotic (H2A). You can then find out how many moles of solid you have used to make up your original solution (in 100ml) and from that (and the mass you used) calculate the relative molecular mass (moles used = mass used/rel molecular mass). It won’t identify the acid, but it will give the possible molecular mass and you could deduce possible formulae. You clearly need more information then to be sure of the identity. Hope that helps, Kevin
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