MadSci Network: Chemistry |
Hello Micheline. You seem to have a good understanding of how salt solutions can conduct electricity. Conductivity is an excellent way to measure the concentration of a salt in solution. Conduction of electricity through a solution requires the movement of positively charged species (cations) towards the negative electrode or cathode and negatively charged species (anions) towards the positive electrode or anode. The conductance of the solution is a measure of the current that flows under a given applied voltage and is proportional to the number of charged particles in solution. SO, with the correct calibration, the conductivity could be used to determine the salt concentration down to very low levels (parts per million). If you want to measure the individual ions present in a mixture of different salts, you would have to do other experiments. For example, you could separate the ions from each other by doing Ion Chromatography and then detecting the individual ions by conductivity. Measurement of conductance can also be used as a way of finding the end point in titrations. In addition to conductivity, other electrochemical techniques include potentiometry, amperometry and voltametry. ElectroAnalytical Chemistry is a massive area, indeed, many undergraduate courses will only scratch the surface. I have searched for good introductory web sites but have not found anything suitable, so I refer you to any good book on Analytical Chemistry for a full explanation of electrochemistry and the various techniques and applications. I hope this helps, Steve.
Try the links in the MadSci Library for more information on Chemistry.