MadSci Network: Physics |
The image of the atom that your have in mind is known as the Bohr atom model. This model was proposed by the Danish physicist Niels Bohr in 1913 for the hydrogen atom, which is composed of one proton and one electron. His idea was based on mixing certain concepts of classical physics with the new the ideas of the quantum that were being developed at the time. Basically Bohr proposed that the electron moves around the proton as if it were a planet orbiting the Sun in a circular orbit. This was not new since physicists knew that electrons had to be moving in the atom in order not to fall upon the nucleus, but classical physics could not explain why electrons did not radiate as a result of their accelerated motion in the atom. Such radiation is predicted by classical physics for any accelerated charge, and would make the electron loose its energy in a matter of seconds and make it fall upon the nucleus anyways. To solve this failure of classical physics to explain the atom, Bohr proposed two postulates that deviate from classical physics. First, an electron in the atom can move only in certain orbits that have DISCONTINUOS values of angular momentum. Angular momentum is a physical quantity that can have any value according to classical physics. Bohr proposed that angular momentum in the atom, only takes discrete values, and after a few algebra steps, this assumption means that the energy of the electron only takes discrete values too. We then say that energy and momentum are QUANTIZED. The second Bohr postulate says that an electron radiates or absorbs one quantum of light when it changes from one orbit to the other. Remember that energy must be conserved, therefore the mechanical energy that the electron looses in a jump from a higher to a lower orbit must be transformed into a quantum of light, which is called a photon. The Bohr model does not explain why this is so, it simply postulates or assumes those two things that are not implicit in classical physics. Why make these two rather unorthodox assumptions? Because they explain rather accurately the observed spectral lines of hydrogen. As you see, assumptions or postulates are made in physics to fit lab measurements. In the Bohr atom model an electron cannot fall upon the nucleus because that orbit is not allowed by Bohr's postulates. This differs significantly from classical physics that allows, for example, a comet to plunge right into the Sun. Such orbit would have a zero angular momentum from the point of view of classical physics. Thus far we have talked of one electron orbiting a proton as in the hydrogen atom. When the Bohr model is applied to atoms with more than one electron, it fails completely to explain the observed spectra. According to the Bohr model electrons in an atom DO NOT necessarily rotate in the same direction or plane, but as you already have noticed, this model still leaves many unexplained questions. Electrons in an atom repeal one another through their electric fields, therefore they don't collide, but their orbits in the atom would be far more complicated that simple circles as in the hydrogen atom. Besides we now know that electrons can have zero angular momentum, so why they don't fall upon the nucleus anyways as the comet onto the Sun? Because of the above problems physicists abandonded the Bohr model for the most part. The problem lies in thinking that electrons behave as particles, and in patching classical physics with quantum physics to explain certain facts. The Bohr model was important because it showed that physical quantities must be quantized at the atomic level, but it was substituted by a more modern approach called wave mechanics, or quantum mechanics. Still today the Bohr model is sometimes useful to understand certain things about the atom, but as you have already noticed, its usefulness is very limited. Unlike the Bohr model, wave mechanics uses a completely different approach that assumes that the behavior of electrons in an atom can be described as waves of density. As the Bohr model, wave mechanics uses a set of principles but they are more fundamental and don't assume concepts of classical physics. Thus it has been far more successful than the Bohr model. According to the modern picture of the atom, electrons can have stable states in the atom. When they change from one state to another, the energy difference is emitted or absorbed as a quantum of light. Electrons cannot really collide with one another, or with the nucleus because they are "waves", not particles, although their states are determined by the presence of the nucleus and other electrons. An electron can be expelled from the atom if it receives enought energy, an can recombine with the atom again by radiating away energy and remain in a stable state. Light is basically a wave of electric and magnetic fields. Therefore light can interact with an electron, which is an electrically charged particle or wave, and this makes it radiate or absorb light and change its state in the atom. Besides quantum mechanics shows that, strange as it may seem, we cannot detect the electron when it changes state. Finally it is possible that an electron collides with the atom nucleus, but not all nuclei can do that and sometimes the electron must have enough energy. This usually happens in stellar interiors or nuclear explosions. For example, the nucleus of the Be 7 isotope can capture an electron and become a Li 7 isotope plus a particle called a neutrino. If you have some physics background, I recommend that you work out the Bohr model formulae following books like Orear's "Fundamental Physics" or some other textbook for first year physics that treats the Bohr model in order to see how classical and quantum physics were mixed rather arbitrarily and still produced the right answer. There are several books that explain wave or quantum mechanics for people with no math or physics background like "Mr. Tompkins in Wonderland" by George Gamow or "Alice in Quantumland : An Allegory of Quantum Physics" by Robert Gilmore or "Taking the Quantum Leap : The New Physics for Nonscientists" by Fred Alan Wolf Vladimir Escalante Ramírez
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