MadSci Network: Chemistry |
Hello, If you have access to a library, a lot of very useful analytical information can be found in Analytical Abstracts. In the indices you may try searching for a few key words like iron, tea etc. Additionally, there are many good analytical text books which deal with Atomic Spectrometry. The techniques for analysis of iron usually involve Atomic Spectrometry. This is a family of techniques which include Atomic Absorption, Atomic emission and Inductively Coupled Plasma (ICP). These techniques involve the apiration of a liquid into the nebuliser of the spectrometer. The nebulised liquid is then drawn into a hot flame or a plasma where gaseous atoms are formed. In the case of Atomic Emission (which includes ICP) the energy from the flame or plasma causes the atoms to populate an electronicaly excited state. The excited atoms relax back to the ground state and emit a characteristic wavelength (this is the same principle as flame tests, and sodium lamps used to light the streets of many towns and cities). The intensity of emitted radiation is proportional to the concentration of the metal ions in solution. It is more likely that you would analyse for iron using Atomic Absorption (AA). Here, the gaseous atoms (in the ground state this time) within the flame absorb radiation from a source, usually a Hollow Cathode Lamp (HCL) which is specific to the element of interest. For example, if you where analysing for iron, you would employ the radiation from an iron HCL. The amount of radiation absorbed is then proprational to the concentration of iron. There are other ways to analyse iron, but atomic Spectrometry would usually be the first choice. Hope this is useful. Steve Lancaster.
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