| MadSci Network: Chemistry |
Hi Tim: You asked what is less reactive platinum or gold? Is hydrogen a
metal as it is in group 1 of the periodic table with lithium Li, sodium,
Na, cesium Cs etc.?
The distinction between metals and non metals is not as distinct as we
often would like it to be. Those elements that easily loose electrons to
from positive ions are called metals. Elements that are metals
have the following physical properties; lustrous appearance, malleable,
high density, good conductors of heat and electricity. They form basic
oxides with oxygen. Metals are electropositive. Metals above
hydrogen in the electromotive series will displace hydrogen from acids.
Hydrogen is, by the above definition, not a metal. It is in group one of
the periodic table because it has one electron in its outermost shell.
--- Dan Berger adds: sometims (very seldom) H is placed in Group 17 of the
periodic table because it can form a basic anion by gaining one electron.
Metals can be grouped in order of their electrode potential. This is
called the electrochemical series. Metals which are higher in the
electrochemical series displace metals which are lower. Hydrogen has an
electrode potential of +0.00.
As to which is more reactive platinum or gold the answer is platinum with
an electrode potential of +1.18 while gold has an electrode potential of
+1.70.
Element Potential (Volts)
======= =========
Lithium -3.04
Potassium -2.92
Calcium -2.87
Sodium -2.71
Magnesium -2.37
Aluminum -1.67
Manganese -1.85
Zinc -0.76
Chromium -0.74
Iron -0.44
Nickel -0.26
Tin -0.14
Lead -0.13
Hydrogen +0.00
Copper +0.34
Silver +0.80
Mercury +0.80
Platinum +1.18
Gold +1.70
A negative value for electrode potential means that the element loses
electrons more readily than hydrogen (i.e., it is better reducing agent).
A positive value for electrode potential means that the element is a poorer
reducing agent than hydrogen.
A strong oxidizing agent has a large positive potential and a strong
reducing agent a large negative
potential.
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