| MadSci Network: Physics |
Well Luc, yours is an interesting and rather difficult question.
Anyway, I'll try to do my best.
The theoretical understanding of superconductivity was advanced in
1957 by three American physicists -John Bardeen (who also worked on
developing the first Solid State transistor), Leon Cooper, and John
Schrieffer-, through their Theory of Superconductivity, known as the
BCS Theory. BCS Theory is extremely complicated and involves many
advanced Solid State and Quantum Mechanics topics (Statistical
Quantum Mechanics, Quantum Lattice Vibrations, Fermion and Boson
Dynamics, Second Quantization ...).
Nonetheless, a naive picture of Superconductivity can be given by
using just
Electrostatics.
According to BCS Theory in a superconducting metal electrons seem to
be in bonded pairs, linked by some attractive force between them.
These pairs of electrons are known as ''Cooper pairs'', and are
formed by a couple of electrons with opposite velocities and spin.
The way electrons are kept together can be thought as follows. As one
negatively charged electron passes by a positively charged ion in the
lattice of the superconductor, it attracts the ion, moving it a
little away from its equlibrium position. Before the electron passes
by and before the lattice springs get back the ion to its normal
position, a second electron is attracted by the ion from its new
position. As a result, an effective force seems to appear between
electrons that tends to put them both closer (i.e. attractive force).
Maybe the following pictures could help to understand this.
| |
------o------------o------ o : Metal ions.
| | - : Bondings between ions.
| | e : Electrons in metal.
| e |
| |
| |
| |
------o------------o------
| |
| |
e | |
-> Step 1: Two electrons with opposite spin and momentum pass by an
ion in the lattice.
| |
------o------------o------
| |
| |
| : |
| : |
\ e |
.o |
------/.\----------o------
| |
| |
e | |
-> Step 2: One of them attracts (and is attracted by) an ion,
distorting lattice order.
| |
------o------------o------
| |
| |
| |
| |
\ e |
o |
------/ \----------o------
e | |
: | |
: | |
-> Step 3: The other electron is attracted towards the moved ion,
resulting in an effective attraction between electrons.
It is through this process that two electrons, which should repel
one another, link up. It is important to understand, however, that
the pairs are constantly breaking and reforming. Because electrons
are indistinguishable particles, it is easier to think of them as
permanently paired.
The electron pairing is favorable because it has the effect of
putting the material into a lower energy state and, by pairing off
two by two, the electrons pass through the superconductor more
smoothly, avoiding electrons' energy to be lost due to collisions
with lattice impurities and deffects (that energy lost is what makes
a metal to be resistive).
As long as the superconductor is cooled to very low temperatures, the
Cooper pairs stay intact, due to the reduced molecular motion. As the
superconductor gains heat energy the vibrations in the lattice become
more violent and break the pairs, so it becomes resistive again.
I hope this answer has been clear enough, althought it is just an
oversimplified view of Superconductivity.
You can find much more details about Superconductivity, as well as
actual BCS Theory, in many graduate and under-graduate level Solid
State books (I strongly recommend you C.Kittel's textbook on Solid
State, as well as N.Ashcroft-D.Mermin's one, which is much more
mathematical but still good).
Here you have also some links to learn more about Superconductivity:
* http://www.ornl.gov/reports/m/ornlm3063r1/contents.html
(Oak Ridge National Laboratory - Tennessee, USA.
Complete and quite good teacher's guide to Superconductivity for High
School students, containing theory, applications and developed
experiments.This has been the main source to my answer, as you can
see.)
* http://superconductors.org
(Website entirely devoted to Superconductors. Theory, products, links
...)
Enjoy, ... and keep on thinking.
Try the links in the MadSci Library for more information on Physics.