MadSci Network: Physics |
Well Luc, yours is an interesting and rather difficult question. Anyway, I'll try to do my best. The theoretical understanding of superconductivity was advanced in 1957 by three American physicists -John Bardeen (who also worked on developing the first Solid State transistor), Leon Cooper, and John Schrieffer-, through their Theory of Superconductivity, known as the BCS Theory. BCS Theory is extremely complicated and involves many advanced Solid State and Quantum Mechanics topics (Statistical Quantum Mechanics, Quantum Lattice Vibrations, Fermion and Boson Dynamics, Second Quantization ...). Nonetheless, a naive picture of Superconductivity can be given by using just Electrostatics. According to BCS Theory in a superconducting metal electrons seem to be in bonded pairs, linked by some attractive force between them. These pairs of electrons are known as ''Cooper pairs'', and are formed by a couple of electrons with opposite velocities and spin. The way electrons are kept together can be thought as follows. As one negatively charged electron passes by a positively charged ion in the lattice of the superconductor, it attracts the ion, moving it a little away from its equlibrium position. Before the electron passes by and before the lattice springs get back the ion to its normal position, a second electron is attracted by the ion from its new position. As a result, an effective force seems to appear between electrons that tends to put them both closer (i.e. attractive force). Maybe the following pictures could help to understand this. | | ------o------------o------ o : Metal ions. | | - : Bondings between ions. | | e : Electrons in metal. | e | | | | | | | ------o------------o------ | | | | e | | -> Step 1: Two electrons with opposite spin and momentum pass by an ion in the lattice. | | ------o------------o------ | | | | | : | | : | \ e | .o | ------/.\----------o------ | | | | e | | -> Step 2: One of them attracts (and is attracted by) an ion, distorting lattice order. | | ------o------------o------ | | | | | | | | \ e | o | ------/ \----------o------ e | | : | | : | | -> Step 3: The other electron is attracted towards the moved ion, resulting in an effective attraction between electrons. It is through this process that two electrons, which should repel one another, link up. It is important to understand, however, that the pairs are constantly breaking and reforming. Because electrons are indistinguishable particles, it is easier to think of them as permanently paired. The electron pairing is favorable because it has the effect of putting the material into a lower energy state and, by pairing off two by two, the electrons pass through the superconductor more smoothly, avoiding electrons' energy to be lost due to collisions with lattice impurities and deffects (that energy lost is what makes a metal to be resistive). As long as the superconductor is cooled to very low temperatures, the Cooper pairs stay intact, due to the reduced molecular motion. As the superconductor gains heat energy the vibrations in the lattice become more violent and break the pairs, so it becomes resistive again. I hope this answer has been clear enough, althought it is just an oversimplified view of Superconductivity. You can find much more details about Superconductivity, as well as actual BCS Theory, in many graduate and under-graduate level Solid State books (I strongly recommend you C.Kittel's textbook on Solid State, as well as N.Ashcroft-D.Mermin's one, which is much more mathematical but still good). Here you have also some links to learn more about Superconductivity: * http://www.ornl.gov/reports/m/ornlm3063r1/contents.html (Oak Ridge National Laboratory - Tennessee, USA. Complete and quite good teacher's guide to Superconductivity for High School students, containing theory, applications and developed experiments.This has been the main source to my answer, as you can see.) * http://superconductors.org (Website entirely devoted to Superconductors. Theory, products, links ...) Enjoy, ... and keep on thinking.
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