| MadSci Network: Chemistry |
Foods are generally complex materials that require digestion before they
can be analyzed for minerals. A chemist would use a spectrophotometer to
analyze for aluminum. The process involves heating to such a high
temperature that the entire sample is vaporized and the vapors are measured
in a spectrophotometer. This machine will read the components of the vapor
and print out an analytical "map". This is a very specialized piece of
equipment that may not be available to you.
You might consider a qualitative method for detecting aluminum to determine
whether or not your cooking method would leach aluminum from the cooking
vessel into the food. I did find a method for testing for aluminum on a
chemistry website from Australia. The website is:
http://www.uq.edu.au/%7Exxjelfic/topic12.html#12.10.3
Below is the method proposed for testing for aluminum:
12.11.4.3 Group 3 Test for Al3+, Cr3+, Fe2+, Fe3+
1.First test.
1.Add 8 drops of NH4Cl solution to 5 drops of the original
solution.
2.Test the solution with litmus paper.
3.Add enough drops of dilute NH3 solution to turn red litmus blue.
1.A green precipitate identifies Fe2+ or Cr3+.
2.A red brown identifies Fe3+.
3.A white glassy precipitate identifies Al3+.
4.If no precipitate forms, go to (Group 4 Test).
2.Second test.
1.Add to 5 drops of the original solution 6 drops of NaOH then 2
drops of NaHClO solution boil then add 2 drops of lead(II) ethanoate
(lead(II) acetate solution)
2.OR
3.Use lead acetate test paper
1.A yellow precipitate indicates Cr3+.
4.(The following common test is too dangerous to be used in schools
because potassium hexacyanoferrate(III) (potassium ferricyanide) reacts
with strong mineral acids to release TOXIC potassium cyanide.
5.Add to 5 drops of the original solution 5 drops of K3Fe(CN)6
solution
1.A deep blue precipitate identifies Fe2+.
2.A brown green precipitate identifies Fe3+.
Note that the experiments above assume you begin with a liquid. Many food
tests start by digesting the food with a strong acid so you have a clear
liquid to work with. Also this method does not indicate how much aluminum
is present, just whether or not any aluminum is there. I have not worked
with this test so I cannot advise you of its practicality. You have a very
interesting project idea, good luck!
Phyllis Stumbo
University of Iowa
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