MadSci Network: Chemistry |
N2 is not used in light bulbs. It is too reactive. Ar (Argon) and another member of Ar's chemical 'family' (Krypton, Kr) are used in light bulbs. Light bulbs pass electric current through a coiled tungsten wire (the symbol for Tungsten is W, from the old name for the element, Wolfram). Tungsten is capable of withstanding high temperatures and has a high melting point (which can be found in a chemical handbook or on a periodic table). So, in the light bulb, the tungsten is heated to a high enough temperature so that it gives off light. In the presence of air (mainly N2 and O2) tungsten heated to the required temperature to give off light would react with O2 and oxidize. This temperature would also be high enough for the tungsten to react with nitrogen (N2 is not as reactive as O2, but at a high enough temperature it WILL react). Gasses on the right side of the periodic table (He, Ne, Kr, Ar) are not very reactive (under some 'strange' conditions they will react, but that's another story). Historically these gasses were not observed to react with anything. In a sense they seemed to be 'above' the need to react with other elements. For this reason they were called Noble gasses. If one heats tungsten in these gasses, so it will give off light, it will not react (burn up), or reacts VERY slowly. I think that Ar or Kr are used in light bulbs rather than He or Ne. I'm not sure why this is the case. Perhaps the tungsten lasts longer in these gasses rather than the others. To find out more, the questioner can go the web sites of General Electric, Sylvania, or Philips. Maybe these sites discuss light bulb manufacturing. Dan Berger adds: Ar is most commonly used in lightbulbs for several reasons: 1. Argon is the cheapest of the noble gases; it can be distilled from liquid air. Krypton is not too much more expensive. 2. Helium and neon are lighter than air, while argon and krypton are heavier than air. This makes argon and krypton easier to use to fill bulbs; you can just pour it in! 3. The atoms of helium and neon are smaller than argon and krypton; this makes helium and neon more likely to diffuse out of the light bulb (and be replaced with air, which is too reactive).
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