MadSci Network: Engineering
Query:

Re: What are the properties of polystyrene, acrylic, perspex and aluminum?

Date: Sun Jan 14 00:02:41 2001
Posted By: James Griepenburg, , Chemical consultant, Chemmet Services
Area of science: Engineering
ID: 978292233.Eg
Message:

Karl,

The answer is "yes, all those materials do what you ask". Before you can 
begin to solve a problem or someone can give you helpful information about 
specific materials the problem must be outlined and then defined.  
Do so; then go to the supermarket or MacDonalds to see how a particular 
situation is solved.  What materials are used and which particular 
properties of these materials are exploited to achieve a certain end.

Polystyrene is a hydrocarbon polymer, a polyvinyl polymer with a phenyl 
pendant group;  Acrylics of which Perspex; aka Lucite, Plexiglas according 
to who makes it, is one, are polyvinyl polymers with ester pendant groups
[polymethylmethacrylate[PMMA]]. They have similar properties, costs, 
recyclability.  Since these have rather bulky pendant groups and atactic
[random] polymerization their strong points are lack of crystallinity and 
good optical properties. They can be made clear.  The acrylics are more 
resistant to oils, etc than polystyrene because the ester groups are more 
polar; the polystyrene resists water and alcohols better.  In any case a 
particular application must be tested for suitability.

Aluminum is a metal. Metals have diverse properties which plastics can 
emulate. In general metals are opaque, conduct heat well by conduction, 
can be made stronger than plastics[esp Al, Fe, Ti] but a given application 
can usually be done by either material. It gets down to Specific needs and 
properties.  Plastics are usually poorer heat conductors than metals, but 
heat conduction is best controlled by construction; see the thermos bottle 
and polystryene cups for examples.  The properties of metals and polymers 
can be nicely combined: steel belted tires; the aluminum-Mylar space 
blanket; the  paper-plastic-aluminum juice containers and many others.  
Aluminized glass or plastic for mirrors. Another property of metals; they 
can be highly reflective of light and heat.  What properties do you need? 
Any material is subject to corrosion, wear and breakdown, chemical 
reaction, and physical trauma and breakage.  these all must be evaluated 
critically in any application.

Costs have to be evaluated critically on a case by case basis.  Examples: 
the steel-tin can has not been replaced by polymer cans altho some are 
used. The glass milk bottle has been replaced by the polymer[polyethylene] 
bottle and the paper carton.  Soda, beer come in glass and cans but beer 
doesn't come in plastic comtainers while soda does.  Wine is just starting 
to sell in plastic jugs but glass is preferred even tho glass is not 
perfect as a container.  Cellophane and waxed paper have been replaced by 
polymer substitutes in many cases. Costs, properties and results are 
intertwined.

Recycling: Any material can be[and should be] potentially recycled.  This 
is a political problem.  Metals are heavily recycled. polystyrene and 
acrylics are not usually recycled put can be and should be.  The Perspex 
company states it will do so for its material.  I, for one, feel that 
manufacturers of any product should be responsible establishing a 
recycling protocol for that product.

If you have specific questions please email them or send them in.

Jim Griepenburg


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