MadSci Network: Chemistry |
Bob, Concerning your experiment, your hypotheses about voltage increases with concentrations (#2) is sound as dictated by the Nernst equation, but be careful of your hypotheses concerning current. Regarding #1, I agree that, at least according to theory, as temperature rises there should be a proportional rise in voltage as dictated by thermodynamics:( if D = "delta", and E = electrode potential, and S = entropy of the system) DG = -nFE = DH - T(DS), or T = ( nFE + DH ) / DS where temperature is proportional to potential (voltage). However, temperature is also proportional to DH (heat). As the voltage increases, so does resistance according to the equation V=iR, where v = voltage, i = current and R = resistance. Between i and R, I believe that a simple experimental setup (regarding wire connections, etc.) will generate a lot more resistance than current... As for #3, you may not see a significant rise in current for similar reasons stated above...
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