| MadSci Network: Chemistry |
Jennifer,
How wonderful that you are having your students answer questions by
experimentation!
I left my copy of the 81st Ed. of the Chemical Rubber Company
HANDBOOK OF CHEMISTRY AND PHYSICS at school, but from the Cornell
University Materials Safety Data Sheet (MSDS) site was able to access the
following density data on the substances you used. The density of sodium
chloride (NaCl), A.C.S., reagent grade is 2.163 g/cm3; sodium hydrogen
carbonate (NaHCO3, AKA: baking soda), A.C.S., reagent grade is 2.159
g/cm3; sucrose (C12H22O11, AKA: table sugar), A.C.S., reagent grade is
1.59 g/cm3; and citric acid, anhydrous, U.S.P. grade is 1.54 g/cm3. So,
to answer your first question, "Of the four, which is most dense?", the
answer is sodium chloride.
As for the solubility, the following data were obtained: sodium
chloride, 36g/100gH2O at 0C; sodium hydrogen carbonate, 8.8g/100g H2O, no
temperature specified (assumed 20-22 C); sucrose, 1g/0.5mL H2O (which is
1g/0.5g H2O) which is equivalent to 200g/100g H20, no temperature
specified (assumed 20-22 C); and citric acid, 59.2g/100g H20. Based on
the available data the solubility of the four substances, the order from
least soluble to most soluble is: sodium hydrogen carbonate, sodium
chloride, citric acid, and sucrose.
May I suggest re-designing the experiment so that you have a control
and controlled variables? You might want to choose sucrose since it is
the most soluble. Set up several containers and add to each of them the
same volume of water at the same temperature. To each container add a
different mass of sucrose and stir until solution is complete. Then add
the same egg, in turn, to each until you determine the solution in which
the egg floats. Using a hydrometer, measure the density of the solution.
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