MadSci Network: Physics |
Dear Chavez, First let me recap both force laws for the benefit of our readers. Newton's Law of Universal Gravitation is: F = G m M / r^2 where F is the magnitude of the force acting on one of the two masses m and M, r is the distance between their centers, and G is a fundamental property of the universe called Newton's constant which describes the strength of the gravitational interaction. If the masses are measured in kilograms and the distance is measured in meters, then G = 6.673 x 10^-11 m^3 kg^-1 s^-2. Coulomb's Law for electrostatics is: F = k q Q / r^2 where F is the magnitude of the force acting on one of the two charges q and Q, r is the distance between their centers, and k is a fundamental property of the universe called Coulomb's constant which describes the strength of the electric interaction. If the charges are measured in coulombs and the distance is measured in meters, then k = 8.987 x 10^9 kg m^3 C^-2 s^-2. As you say, there are many similarities in the form of the two laws. There are also restrictions that apply to both laws: the masses or charges must be either mathematical points or spherically symmetric distributions of mass or charge. Finally, both forces are "central" meaning that the direction of the force is along the line joining their centers. Now to your question. > ... in chemistry, the bigger the atom (or bigger ionic radii), the > less attractive force it has with it's bonded partner. Why not the > bigger the atom, the higher the force of attraction? The force in Coulomb's Law depends on the CHARGES of the ions, not their MASSES. The charges of the ions depend on the number of electrons exchanged to form the bond, and have nothing to do with the size of the atom. Remember that atoms are electrically neutral; the positive charge of the protons in the nucleus is cancelled exactly by the negative charge of the electrons surrounding the nucleus. When two neutral atoms form an ionic bond, one atom loses some electrons and the other atom acquires the same number of electrons. This determines the charges q and Q that appear in the numerator of Coulomb's Law. As an example, consider two salts: sodium chloride and cesium iodide. Both sodium and cesium have one electron in their outermost shells; both chlorine and iodine need one electron to complete their outermost shells. When sodium and chlorine bond ionically, the sodium atom donates one electron to the chlorine atom. The sodium atom (now an ion) has a charge of +1e and the chlorine ion has a charge of -1e, where e is the absolute value of the charge of one electron, e = 1.602176 x 10^-19 coulomb. These are the charges q and Q to be used in Coulomb's law. The distance r is the sum of the radii of the sodium and chlorine ions. When cesium and iodine form an ionic bond, the charges are +1e and -1e respectively, the SAME q and Q as in sodium chloride because in both cases one electron is exchanged to make the bond. The distance r is different this time; it is the sum of the radii of the cesium and iodine ions. This new r for cesium iodide is larger than the r for sodium chloride because the cesium ion is larger than the sodium ion, and the iodine ion is larger than the chlorine ion. Coulomb's Law predicts correctly that sodium chloride is more tightly bound than cesium iodide. > Lastly, if the size of Earth increases, does that mean the force of > gravity acting on me would increase? If so, why? The answer depends on which values you change and which values you hold fixed. If the radius of the Earth increased while the mass of the Earth remained fixed, then the force of gravity acting on you as you stood on the Earth's surface would decrease. Why? Consider Newton's Law of Universal Gravitation; leave the masses m and M alone and increase the radius r. Clearly the force F would decrease. However, if both the mass and the radius of the Earth increased while the density (mass per volume) remained fixed, then the force of gravity acting on you at the surface would increase. --Randall J. Scalise http://www.phys.psu.edu/~scalise/
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