MadSci Network: Chemistry |
Aah yes, goopy
stuff!. I guess the glue you used was white school glue; let's start
with that. That's made with polyvinylalcohol (PVA), or maybe you
used "latex glue". This sticky stuff is basically a latex suspension, that
is a mixture of very small rubber particles in water (the usual odor of
ammonia is real... it is there as a preservative). Both PVA and this
natural particular rubber ("cis 1,4 polyisoprene" to be exact) are
polymers (you probably guessed that from their chemical names). OK, so
let's get down to the nitty gritty... what's a polymer? Ready for some
Greek? Poly means many or much, and "mer" comes from meros
meaning part. Just think of a polymer molecule as simply thousands (even
millions) of the same building block molecule ("monomer") joined
together. Maybe like those plastic beads young girls snap together to
make bracelets and necklaces. Linear polymers like these glues are just
as wiggly as that end-to-end bunch of beads. So what's up with the borax
(sodium borate)? The borax is a "cross-linking" agent. It actually
reacts with the rubber molecules forming bridges between strands of linear
polymer. Now the rubber becomes more solid but can still flex... even
spring back into shape - its not entirely rigid (these crosslinks are not
too strong). Plus there's still a lot of water around when you make the
goopy
stuff and that gets caught up in the cross linked polymer.
Too much water (weak glue or the washable type) and the goopy stuff is
slimey rather than "rubbery". You've probably heard of "vulcanization" of
rubber. That's another method of crosslinking, normally using sulfur.
See also
Could
you please help me with molecule and polymer?
and
Wha
t holds rubber together?
Goopy wishes!
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