| MadSci Network: Chemistry |
Hi, Tim. Who says you should care when eating out of a plastic container?
Millions do it every day. Witness Rubbermaid, Gladware and Tupperware for
example. These plastics have been vigourously tested for safety. These
products are made from polyethylene. Water and foods are packaged in
polyethylene in the form of plastic bottles, squeeze bottles and the like.
Ethylene containers hold milk while others contain vinegar. They are
strong, safe, flexible and reliable.
Other food containers are made from polypropylene. These plastics are
designed and tested to contain such foods as margarine, yogourt, cottage
cheese, sour cream and other such tub containers. They were not designed
to be continually reused to store other foods in. Polypropylene does have
the tendency to adsorb molecules so that off odours or tastes can occur if
reusing repeatedly over a long period of time. Storing acidic foods may
be problematic as some of the plastic could break down. Practically this
wouldn't make much difference as these amounts are barely measurable,
(i.e. in the parts per billion). However, due to the litiguous
environment prevalent in the United States, companies that manufacture
these products prefer to err on the side of caution and recommend only
what the products have been tested and designed for.
The main debates in the scientific community regarding plastics are with
plasticizers. These are substances added to plastics to make them more
flexible, pliable and tough. Phthalates are among the more important ones
used, as well as tricresyl phosphate. They are used in plastics such as
polystyrene, vinyl, like P.V.C., and polyacrylics. The worry is that they
can leach out and cause people to become ill. Rats, (bred to be sensitive
to carcinogens) have shown increased liver tumours and smaller testes when
exposed to plasticizers like DEHA (diethylhexyladipate). Swedish workers
exposed to plastics and plasticizers on a daily basis had higher levels of
testicular cancer. However, apart from occupational and environmental
concerns they have not been proven to be harmful in the general
population. A 1990 E.U. commission did not find DEHA to be a carcinogen in
fish, hamsters, guinea pigs, dogs or monkeys. The Danish Institute of
Toxicology concluded that an intake of 500 mg./ day was without effect on
humans. Our average daily intake is about 0.35 mg. Over a lifetime
that's less than 10 grams, (about a dessert spoonful).
Another concern with plastics is a compound called bisphenol A which is
used as an intermediate in the manufacture of some plastics like
polycarbonate, baby bottles or in the inside lining of some canned foods.
This compound has estrogenic properties and its long term effect on humans
is unknown. It falls into a category known as endocrine disrupters.
Where large amounts of these types of pollutants have been found some
observational studies have noted the following: female birds displaying
gender reversal roles, smaller alligator penises and gender differences in
fish. Keep in mind that bisphenol A has never been proven to be harmful
in humans.
Glass is a stable and impervious material. You aren't ingesting glass
with your meal. Clay has been used for thousands of years and is also
safe and non-toxic. Ceramics are generally safe as well, although there
have been some isolated cases of some ceramics (especially in the late
1980's), which were found to leach lead. Most of those either came from
Third World countries or were not fired properly. The best ceramics
are 'ceramic glass' such as Corning Ware' (TM), that are safe and can
withstand high heat.
As for your homemade beer, I wouldn't use the paint containers. Plastics
can absorb contaminants which could not only cause off tastes and smells
but may contain undesirable chemicals that may not exactly be good for
your health. Stick to the adage "If it wasn't meant for food - don't use
it."
Finally, that airplane seatbelt is not as useless as you might think. Not
wearing it has actually caused serious injury and even death during
violent turbulence. I guess that strip of polyester around your waist may
gain some new respect. Hope that helps.
Peter Bosani.
Sources: Dr. John Emsley- Molecules at an Exhibition.
Dr. Joe Schwarcz- Radio show- C.J.A.D. Montreal. May 04 & 11, 2003.
Hawley's Condensed Chemical Dictionary.
As well you may want to read - Plastic- The making of a synthetic century
by Stephen Fenichell.
Try the links in the MadSci Library for more information on Chemistry.