MadSci Network: Physics |
Hi Ken, thanks for your question: I should say questions! You asked how the kinetic energy of atoms and molecules, for example atoms in a plate of iron is translated into radiant energy when the iron is heated to a sufficiently high temperature to emit not just heat but visible light. We call the radiation for example “thermal radiation” if it is not sufficiently energetic to contain visible light or “incandescence” if visible light is emitted. You also asked how much energy do you need to emit a photon. This second question is a little easier to answer. Whatever the process responsible for producing the photon, the energy needed is at least the amount of energy possessed by the emitted photon. This energy is calculable from the wavelength of the photon of radiation emitted. The energy of a photon (E) is linearly related to the frequency of the light (f) and the constant of proportionality is known as Planck's constant (h) such that E=hf. Planck's constant is around 6.626*10-34 Js. To produce a visible photon the energy needed is very high compared with the energy of normal thermal vibrations at an atomic level. The more difficult issue is how the transformation of energy occurs. I like this type of question because it gets down to basic physical behaviour. This shows that you are not satisfied with just knowing the laws which describe phenomena but want to be able to explain them. This is a good attitude. Heat energy in any body is the energy which is associated with the vibrational motion (and rotational if rotation is possible) of the body’s atoms and molecules. The more heat the body contains the more energetic these vibrations and the buffeting that the atoms and molecules experience become. Teir motion gets more violent and faster. Atoms and molecules contain the positively charged nuclei and the surrounding “clouds” of negatively changed electrons. As a result of the turbulent oscillating motions these charges are continuously being accelerated one way then another. Scotsman, James Clerk Maxwell developed the theory and predictive equations linking the acceleration of charge with the generation of a wave of electrical disturbance we know as electro-magnetic radiation. Accelerated charge causes the emission of this type of radiation and conversely absorption of radiation causes acceleration of charge. This is how radio aerials and receivers work and explains the processes of light absorption and emission in atoms and molecules. I had some difficulty finding a reference to confirm this explanation for thermal radiation. The best I found was Michael Fowler’s http://galileo.phys.virginia.edu/classes/252/black_body_radiation.html You asked whether this kinetic energy is a fixed amount as with photons. This is also an interesting question too especially because of the link between the phenomenon of thermal radiation and the beginnings of quantum theory. It is true that thermal motion is quantised, that is not all values of the energy of the motion are allowed. In practice, in bulk materials heated to temperatures sufficient for them to visibly glow, there are so many different levels of energy available that the light emitted continuously varies across the range of wavelengths emitted. However when people tried to explain the distribution of light energy emitted by black bodies (ideal emitters which absorb all wavelengths completely) the predictions were not always good. Max Planck rightly put more faith in observation than theory and his attempts to improve the predictions involved the assumption that the vibrational energies were quantised. The predictions were then substantially accurate and this improvement was seen as strong evidence for the quantisation of energy. Physics never looked back !
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