| MadSci Network: Physics |
This appears to be degenerate perturbation theory.
There are two benzene states |a> and |b> with the same unperturbed energy
E_0. There is a small perturbation V that connects the states,
with A=. Thus, "the easier the flipping back and forth between the
two states, the higher the coefficient A".
This gives a 2X2 matrix |E_0 A |
| A E_0|.
The perturbed energies are obtained by diagnolizing this matrix,
resulting in energies E_1=E_0+A and E_2=E_0-A.
Thus, "the higher the coefficient A, the higher the energy separation
between the two states."
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