MadSci Network: Chemistry |
I will assume weak-acid weak-base vs. strong-acid strong-base reactions for simplification. The heat released or enthalpy of neutralization is dependent on the concentration of H+ (H3O+) and OH- . In order for H+ to form, the acid-H of the molecule must ionize in solution. Strong acids always completely ionize in solution unless the concentration is extremely high, but normally this is not the case. This means that there is a complete neutralization of all available acid-H. Weak acids however by definition do not completely ionize in solution so the concentration of H+ is never equal to the total available acid-H. Therefore full neutralization of the acid is never achieved and so cannot produce as much heat as the same molar amount of a strong acid.
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