MadSci Network: Chemistry |
All around us we have gas at a reasonably high pressure. In outer space there is a vacuum. The gas laws say that gas under pressure ought to expand into a vacuum. So what is going on? Is the Earth in some sort of container that stops this expansion? Or is there continuing expansion going on, with the atmosphere being replenished somehow? The Earth is not within a container, in any sense. The gases in the Earth's atmosphere are not undergoing continuing expansion either. The gas laws you are thinking of are ideal gas laws, and they leave quite a number of things out of consideration. They work very well for smallish samples of gases that are well above their condensation points. But they do not take into account many other effects, and gravity is one of these effects. The Earth's atmosphere is held to the Earth by gravitational forces. It is under pressure, because each bit of atmosphere is "squashed down" by the weight of the column of gas above it. An important "gas law" when you are thinking about the atmosphere is the barometer equation, which deals with this situation: ln (p/p0) = Mgh/RT --where p is the pressure at altitude h above some reference altitude (e.g. sea level) where the pressure is p0; M is molar mass of the gas; g acceleration due to gravity; R gas constant; and T absolute temperature. As you go higher, the air very rapidly gets a lot thinner. If you calculate the terms on the right hand side using M = 29 g/mol, g = 9.8 N/kg, R = 8.314 J/mol/K, T = 240 K, you come up with ln (p/p0) = h / 7 km. This means that the Earth's atmosphere has a pressure which halves for each 5 km of height, or falls by a factor of 10 for each 16 km of height. This is roughly correct. It is not accurately correct because 1) The atmosphere is not at equilibrium, but is turbulent -- especially the bottom bit where all the weather systems are. 2) The temperature of the atmosphere is different at different heights, and varies in quite a complicated way. In the equation I substituted 240 K -- about -33 deg C or -28 deg F -- as an average value. But different parts of the atmosphere can be a lot hotter or a lot colder than this. 3) The atmosphere is made up of a mixture of gases, not a single gas. Below about 80km, it is well mixed by air currents, and no separation of gases occurs. But above that height mixing occurs mainly by diffusion, and lighter gases move to the top, so that in the very outermost parts of the atmosphere there are layers of lighter gases like helium and hydrogen. In the solar system away from planets, there is a fairly good vacuum. Scientists do know what the pressure and composition of the "interplanetary medium" is. It contains much less that a trillionth as much gas per cubic metre as the air that we breathe. And it is about 95% hydrogen, 5% helium, with traces of water and methane.
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