MadSci Network: Physics |
Steve, There are two flaws in your argument. The first is in your mathematics. If S=H/T and both H and T are negative, then S will be positive. More important to me is the flaw in your physics. It is not true that if the temperature decreases, the heat must decrease. Heat and temperature are related, but very different things. I can offer two brief examples. When you melt ice, the ice is absorbing heat, but its temperature will not change until all of the ice is melted. You can see this yourself if you freeze a thermometer into a beaker of ice overnight so that it is nice and chilly (perhaps -10 or -20 degrees C) the next day. Then put the beaker on a table or a slightly warm surface that will heat the beaker up (a hot plate on a low setting will work). Take the temperature of the ice every couple of minutes. When the temperature reaches 0 degrees C, you will notice that the rise in temperature levels off as the ice turns to water. When the substance becomes entirely water, the temperature will begin to rise again. The point is that while the ice is changing phase from solid to liquid, it is absorbing heat while the temperature remains constant. The second example I have is the adiabatic expansion of a gas. In an adiabatic expansion, no heat is lost by the gas. This is the situation that exists in either a very rapid expansion or in a well insulated expansion. As the gas expands, its temperature must decrease (both the pressure and the volume are decreasing, so the temperature must also decrease) but the amount of heat in the gas remains constant. This second example best describes the expansion of the universe. Often when you see the expansion of the universe described, you will see the term "adiabatic expansion" used. The reason for this is that there is nothing for the universe to exchange heat with and so the expansion must be adiabatic. Actually, apart from what I have pointed out here, your arguments are quite sensible. One of the acid tests of any theory is to stack it up against the second law of thermodynamics, and it is with this sort of analysis that objections to theories are raised. Often it results in a better understanding of the physics as the situation is reviewed in a new light. So keep asking questions like this one!
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