| MadSci Network: Physics |
To answer the first part of your question, it is very possible for ice to exist at lower temperatures than 32 degrees Fahrenheit. For example, it is almost always colder than that temperature in Antarctica, and the ice there would be approximately the same temperature as the surroundings (at least at the surface). Ice has been studied at temperatures down very close to absolute zero. You are almost on the right track, however, because there is an ice- related temperature that is constant. That is the temperature of a *mixture* of ice and liquid water. If ice and liquid water are coexisting at normal atmospheric pressure (provided you are at an equilibrium condition, which would take some time if, for example, you dropped an ice cube into warm water), then that means you are *exactly at* the freezing/melting transition, and the temperature is 0 degrees Celsius (32 degrees Fahrenheit). Scientists sometimes use this invariant temperature to calibrate thermometers. It doesn't matter whether you have 99% ice and 1% water or vice-versa, since the temperature doesn't change during the transition having the 2 phases coexisting means you are at the unique transition temperature. As for those citrus growers, I'm not certain, but I think what they are doing is trying to maintain coexistence between liquid water and ice on the exterior of the fruit. As long as you have that coexistence and it doesn't completely freeze, the temperature there will be 32 degrees Fahrenheit. Since the juices inside the fruit are solutions of sugar, etc. in water, their freezing point is a little lower than 32 degrees F (you can look up "freezing-point depression" for an explanation), so the water/ice coexistence on the surface would protect the fruit from freezing. ---------------------------------------------------- Dr. Allan H. Harvey, Boulder, Colorado, steamdoc@aol.com
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