MadSci Network: Chemistry
Query:

Re: How does Zero Gravity softdrink(soda)work

Date: Wed Jun 16 01:48:56 1999
Posted By: John Christie, Faculty, School of Chemistry, La Trobe University, Bundoora, Victoria, Australia
Area of science: Chemistry
ID: 928995382.Ch
Message:

I have not come across this product, so I am a little in the dark about its 
exact behaviour. Either I have not been checking the soft drink cabinet in 
the local milk bar thoroughly enough, or the product has not yet penetrated 
South of the border! So I will have to answer the question by imagining
what would need to be done to achieve a product of this sort that "works".

After that bit of Australian, I will have to try strenuously to speak North
American. So we have soda and drugstores, etc. But most importantly I am 
told that "little jelly beads" does not scan. So I will try "little lumps 
of jello". I am referring to items about 2 to 5 mm in diameter which are 
gelatinous, soft, wobbly, non-sticky, and edible (as I believe you are 
too!).

There is a very interesting phenomenon called "neutral buoyancy". If you put a stone in water, it sinks to the bottom; if you use a lump of wood instead it floats. The density of rock is greater than that of water, while that of wood is less. If you make a material with a density that is almost exactly the same as that of water, it will neither float nor sink, but wander around fairly freely, following the convection currents in the water. Sometimes it might adhere to a wall of the container or something like that and spoil the effect.

You can see much the same thing after a party with helium balloons. Several of the balloons will have escaped and lodged themselves on the ceiling. But helium slowly leaks through the skin of the balloons, and after a while (a few hours) the lifting power of the helium in the balloon is just exactly enough to carry the balloon and its string. Ten very interesting minutes follow during which the balloon wanders quite freely around the room on the air currents, before it loses enough extra helium to start dragging its string on the floor (you can revisit the phenomenon by cutting the string shorter!).

It is this same phenomenon of neutral buoyancy that we want to obtain in our soda. The problem is to design the jello. Soda is a particularly difficult medium to work with because of those little bubbles; Floating jello lumps in a still drink would be a lot easier to achieve. The important things are

  1. The jello must be made of an approved food material
  2. The jello must be indefinitely stable in water -- it must not dissolve or get sticky
  3. The jello lumps must remain individual; they must not stick to one another or to the walls
  4. There is a need to consider how the bubbles interact with the jello lumps
In the context of this last point, there is a concept that surface chemists call the "hydrophilicity" (roughly Greek for water-loving-ness) that can be controlled for different effects. Jello lumps can be made water-repellent or water-attracting. Gas bubbles will readily adhere to water-repellent jello lumps, and carry them to the surface. A strongly water-attracting jello lump will be little affected by gas bubbles. We could make a product with slightly water-repellent jello lumps that were denser than water, so that they would sink to the bottom while the bottle remained closed. But when the bottle was opened, gas bubbles would cling to the jello lumps, lifting them to the surface, where they would lose their bubbles and start to sink again until they had enough bubbles to lift them again, and so on. Fine control would be needed though, because if the jello lumps were not heavy enough, or too water-repellent, they would simply spend all of their time sitting in a froth at the surface. The other way to go would be to use jello that was the same density as water, and extremely water-attracting, so that bubbles would not adhere to the surface of the lumps at all, and you would have neutral buoyancy whether the bottle was opened or closed.

To stop the jello lumps from sticking to one another or to the walls, there is another surface chemical trick. The conditions are arranged so that the jello gets a surface electrical charge in the soda solution. All lumps get the same charge, and like charges repel. If the charge is the same as that at the bottle walls, the lumps will also stay clear of the walls.


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