| MadSci Network: Chemistry |
Rodney,
The reason why metallic catalysts are usually used in the form you
mention is related to the chemical mechanisms by which they act. The
catalysis occurs on the surface of the metal; the rest of the metal does
nothing. So, the greater the surface area, the more efficient the catalyst
will be on a pound-for-pound basis. Some metal catalysts such as palladium
are expensive, which provides a financial incentive to maximize the amount
of metal that is catalytically active. Thus catalysts are often used as a
film over some other, cheaper support material.
In most cases the metal surface serves to bind the two reactants and to
lower the activation energy for the chemical reaction between them. One
example is a catalytic converter in an automobile. The metal catalyst
binds oxygen molecules from the air. Exhaust gases, containing
incompletely oxidized hydrocarbons, pass over the catalyst. Some of these
organic molecules bind to the surface where they are further oxidized by
the metal-bound oxygen before being released.
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