MadSci Network: Chemistry |
Rodney, The reason why metallic catalysts are usually used in the form you mention is related to the chemical mechanisms by which they act. The catalysis occurs on the surface of the metal; the rest of the metal does nothing. So, the greater the surface area, the more efficient the catalyst will be on a pound-for-pound basis. Some metal catalysts such as palladium are expensive, which provides a financial incentive to maximize the amount of metal that is catalytically active. Thus catalysts are often used as a film over some other, cheaper support material. In most cases the metal surface serves to bind the two reactants and to lower the activation energy for the chemical reaction between them. One example is a catalytic converter in an automobile. The metal catalyst binds oxygen molecules from the air. Exhaust gases, containing incompletely oxidized hydrocarbons, pass over the catalyst. Some of these organic molecules bind to the surface where they are further oxidized by the metal-bound oxygen before being released.
Try the links in the MadSci Library for more information on Chemistry.