MadSci Network: Engineering |
The experiment you are performing is easy to conduct but difficult to explain so I hope you will be patient with me. When we attempt to conduct a current through any object, we are simply attempting to move electrons through the object. For the electrons to move, they have to have the assistance of "charge carriers," or simply put, something that will help them move through the object. The following link gives some brief information on the topic of charge carriers: http://www.britan nica.com/eb/article?idxref=307153 In metal wires, electric current flows by the movement of free electrons within the metal. Gases and liquids normally don't have free electrons; the way that current flows through a gas or a liquid is usually by hitching a ride on charged particles called "ions." When some compounds are dissolved in a liquid, they tend to break into positive and negative parts called ions. For example, when you dissolve citric acid in water, part of the citric acid molecule forms a positive H+ ion, with the remaining part of the citrate molecule forming a negative ion. Table salt is another good example of a molecule that forms ions in water. Many other molecules, such as sugar and oil, do not break apart to form ions. So, sweetness of a piece of fruit has nothing to do with electrical conductivity, but tartness does. Normally, the electrical conductivity of a solution depends upon the kinds and numbers of ions present. A really acid fruit, such a lemon, has a lot more citric acid than an apple or a pear, so normally, there are more ions present, and the lemon will have higher conductivity than the apple or pear. And conductivity within the fruit is determined by the chemistry of the liquid; the solid parts of the fruit are insulators. Now, things get a bit complicated. If you attempt to pass a low voltage direct current through your piece of fruit, when you initially supply voltage to the electrodes you have placed in the fruit, the positive ions in the fruit are attracted to your negative electrode, and the negative ions are attracted to your positive electrode. Initially, a few electrons appear to pass through the solution. As the ions collect at these electrodes, the current stops flowing; each electrode is surrounded by oppositely charged ions and so there is no path for an electrode to get all of the way from one electrode to the others (kind of like girls surrounding the stage of a rock star; he cannot get through the barrier of girls to the exit at the other side of the building). What is formed is called a double layer, and is used to make very high energy storage devices called "ultracapacitors." The double layer acts as a very good insulator once it builds up. So, if you want to pass a current through an electrolyte, you really have two choices. First, if you increase the voltage to maybe 5 volts or so, there is enough energy for the water in the fruit to break down into hydrogen and oxygen. You chemically blast apart the double layer. Because you are actually performing a chemical reaction at each electrode, electrons are consumed at one electrode and produced at the other electrode, so the current appears to flow through the fruit. There will be a voltage drop of about 1.2 volts through the piece of fruit, and more acid fruits should conduct more current than those with less acidity. The second choice is not to attempt to pass a direct current through the fruit, but rather pass an alternating current through the fruit. With an alternating current, current flows in one direction, then stops and flows in the opposite direction. Current supplied by transformers and by the power company is alternating current. Within the US, the current alternates 60 times per second; in some other countries, the current alternates 50 times per second. Using alternating current, the fruit is acting like a capacitor in the circuit; each time the current reverses, a few electrons are squeezed out of each electrode before the double layer builds up. When companies build meters to measure conductivity in liquids, the circuits they use almost always use alternating current to avoid the double layer problem. So, you can try using something like a battery charger which produces a high enough direct current to decompose the water within the fruit to demonstrate conductivity, or you can use an alternating source of current like a toy train transformer to avoid forming a double layer
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