MadSci Network: Chemistry |
Terri, Specific gravity is simply the weight per unit volume expressed [usually] in grams/cubic centimeter. In the laboratory we use a device called a pycnometer for determining the specific gravity of liquids and solids. In testing a liquid, the pycnometer is a small flask fitted with a hollow stopper. The liquid under test is placed in the flask and the stopper inserted fully [which causes an overflow]. The weight difference [empty-full] divided by the volume [provided by the pycnometer manufacturer] is the sg. If the volume is not known, repeat the experiment with water as the reference liquid [at the same temperature, of course]. using the sg of water as 1.0 [or go to the CRC Handbook for exact values] you can calculate the volume. For solids, the pycnometer is usually a fully automated instrument. Lacking one, you need,once again,the weight and volume. The first is no problem and the second [volume] is usually done with a displacement technique by adding the known weight of an unknown substance to a known volume of a non-solvent and reading the new volume providing, of course, that the unknown sinks and does not float. Specific gravity remains one of the most fundemental tools of an analyst. Ken Johnsen
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