| MadSci Network: Chemistry |
Question: "How and what is toner for copiers made of ?" "I have learned that not all toners are the same. For instance one make of toner will not work on another make of machine or even in the same range of machines there are differences. I was told that it has something to do with the way it is made during manufacture ?" This is not my field of expertise but I know a little bit about how electro-photography works and it may be enough to answer the question Answer: As is the case with most systems, each component is designed with other parts of the system in mind. The designer will start with performance requirements dictated by the customers' needs. Whatever results are needed, all parts of the system will need to work together. Let's briefly remind ourselves about electro-photography and how the toner needs to behave. The image of the object to be copied, for example a document or photograph, is projected onto a photo-conductive surface which has been given a uniform electric charge. Where light falls in the surface the charge can leak away leaving a "latent image" of charge on the surface. The surface is then treated with toner. This is either dispersed in a non-conducting liquid or is a powder. Most photocopiers use powders. The particles of toner are charged and are attracted to the oppositely charged latent image. The image made up of toner is then transferred onto the paper and heated above its melting point. It flows into the paper and on cooling becomes solid again. If the image quality needs to be high or the speed of operation needs to be very fast, the machines and materials will be designed appropriately. Toner for colour photocopiers consists of a pigment, usually solid organic dyes, and a polymeric binder, for example a polyester or styrene acrylate. The purpose of the binder is to hold the pigment in place in the final image. It also provides gloss to the image areas. In Black toners using carbon, the binder prevents the charge leaking away from the charged toner particles. If the quality needs to be high the toner needs to be made from very small particles, for sharpness and graininess, and it would need to contain pigments with good colour characteristics. The way the machines work also dictates what other characteristics the toner needs to have. It has to be charged up and this can done in a number of ways. It has to retain the charge until it is fused. Each machine type will have different toner handling systems and anticipated operational conditions. The pigments and the polymer binders influence the ease of charging and the stability of the charge on the toner particles. The melting point of the toner is a good example of the interaction of the equipment and the toner. It would be no good using a toner with a high melting-point in a machine which didn't provide enough heat. I found a web site with some information about manufacturing methods. http://www.zeon.co.jp/en glish/new/f/f-tec13.html This article "Polymerized Toner: Its Feature and Future" describes a method of producing smaller more evenly sized particles than the normal type in which pigment is mixed with molten polymer. The cooled mixture is broken into small particles by a milling process. The newer method involves producing a homogenised emulsion of monomer containing the pigment and then polymerising the monomer to produce the toner. The resulting imaging improvements are indicated. Another article on the site "tec-7" or "Preparation of the Polymerized Toner" shows pictures of the polymerized and milled toners showing the more spherical, smaller particles in the new type of toner.
Try the links in the MadSci Library for more information on Chemistry.