MadSci Network: Chemistry |
As a high school chemistry teacher, every book we teach from explains bonding as a phenonemon that occurs so that atoms can fill their valence shells. I am really questioning this now. Why? For a few reasons. Let us look at sodium and chlorine forming sodium chloride. (1) Chlorine when it gains an electron actually increases its size, increasing the potential energy between the electrons and the protons! Bad. (2) Sodium, we tell the students wants to lose an electron so to have an electronic configuation like Neon, but it requires energy to take this electron away! Bad. Sodium and Chloride combining is driven by the ionic bonding step, not the formation of the ions. Is it that sodium can give an electron fairly easy, and is left with a full valence as a consequence only and chlorine can grab an electron because it has a good electron affinity, and it has a place for it in the valence shell. Both of these do not necessarily mean that having a filled valence shell is important. I am now wondering why we tell the students that filling the valence shell is the driving force for bonding. What energy is minimized when the valence shell is filled for simple atoms (periods 1-4 let's say)? Is it some sort of quantum energy? If it is I would like to know fairly simply and explicitly.
Re: Why is filling the valence shell so important?
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