MadSci Network: Chemistry |
According to IUPAC rules, you need to name a compound based on the longest LINEAR chain possible. For example if you have CH3-CH2-C(CH3)H-C(CH3)H-CH3, although there are 7 carbons in all, the longest straight line chain consists of 5 carbons. The other two CH3 groups are branches. The basic name thus becomes pentane, not heptane. To then indicate the presence of the other two groups (CH3=methyl), we use the full name 2,3-dimethyl-pentane. The "2" and"3" indicate that the second and third carbon atoms within the pentane chain are where the branches are located, the di- indicates that there are two methyl groups. ( We use the lowest #'s possible to indicate position; so it would be incorrrect to use 3 and 4 if you started to count from the left hand side) If instead of CH3, you had the following chains, you would then use the corresponding names that I've included: CH3CH2----ethyl CH3CH2CH2---propyl CH3CH2CH2CH2--butyl For more details, clearer structural formulas, and more examples, consult the organic chemistry text Organic Chemistry by Solomon or Organic Chemistry by Boyd or email me with specific examples at enricouva@hotmail.com
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