MadSci Network: Chemistry |
I am not in a position to give you any very specific leads. The two areas to look at are: (1) There are a lot of publications (well, a few, anyway!) in the specialist Philosophy of Science area. Emergent properties raise some very interesting philosophical issues, and there have been several attempts at analyzing the basis of these properties at a philosophical/metaphysical level. (2) There are relevant publications in the area of 'Systems Analysis'. Systems Analysis seems (from my external and nodding acquaintance) to be a field with a bit of a split personality. A lot of it is about computer organization and computer networks, and is very specialized and specific. But there is also a much broader discipline to do with the way that assemblies of various sorts of components operate. It seems to be mostly tackled by Engineers and Mathematicians. Apart from these two areas where emergent properties are examined and discussed as such, I am not aware of any general discussions of emergent properties, but there is a lot of stuff about individual and specific emergent properties. To take just one example for starters, the whole of statistical thermodynamics is about trying to calculate bulk properties of materials from the known or assumed properties of their microscopic atoms and molecules. I will conclude this answer with a couple of examples to illustrate just what we mean by 'emergent properties' to make sure that we are on the same wavelength, and that third parties reading our correspondence will be in the picture. Example 1: The behaviour of traffic. Traffic is just a group of motor vehicles, operating in an environment consisting of a road surface, some weather conditions, and possibly some road rules and flow control devices. You can analyze any of these components as thoroughly as you want to, but you will not be able to predict the behaviour of a phenomenon like a traffic jam/motorway snarl/ gridlock (paying due homage to local variants of the English language) from the behaviour of any of the components, or even the interaction of simple combinations of them. The way that the traffic gets blocked and then possibly manages to start to clear itself again cannot easily be related to the way a motor or a braking system or a speed limit works. It is only by putting a complex simulation of a large number of vehicles and their operating environment together that we can get any sort of model of the situation. Example 2: Metals. There is a set of properties by which we know and recognize certain substances as metals. It is not a clear-cut category -- there are borderline cases. But there is a characteristic set of physical properties that goes with being a metal: Metals are opaque, with a lustrous surface when clean. Metals are good conductors of heat and electricity. Solid metals are somewhat plastic -- they can be beaten into thin sheets, or drawn into wires. Many metals (silver, gold, copper, lead, zinc) are simple substances, made up of only one type of atom. Others are alloys of different elements (steel, brass, bronze, pewter). So we say that gold, silver, lead, etc. are 'metallic elements'. But there is no sense in which an atom of a metallic element shows any of the distinctive properties of the metal. The opacity and lustre of a metal can only be seen when at least tens of thousands of metallic atoms get together. Bulk conductivity of heat or electricity is not expressed until we have layers 50 or 100 atoms thick -- quite a different set of phenomena governs the transfer of heat or current over shorter distances. And you need a cluster of about 20 or 30 atoms to define a condensed phase, a much larger number to decide whether it is solid or liquid, and a larger number still to determine whether there is plasticity in the behaviour of the solid. All of the characteristic properties of metals are emergent properties of a large cluster of atoms of a metallic element. They are in no sense properties of the metallic atoms themselves.
Try the links in the MadSci Library for more information on Chemistry.