MadSci Network: Chemistry
Query:

Re: Where does Yellow Prussiate of Soda(Sodium Ferrocyanate) come from?

Date: Tue Oct 10 15:04:23 2000
Posted By: Mark Schneegurt, Assistant Professor, Biological Sciences, Wichita State University
Area of science: Chemistry
ID: 970273169.Ch
Message:

The simple answer is no.

I am not a chemist by training, but this is what I have learned about yellow 
prussiate of soda.  It is added to rock salt and foods to prevent caking.  
Kosher salt typically has yellow prussiate added to it.  I contacted the 
folks at Morton Salt and they said that yellow prussiate does not naturally 
occur in salt deposits.  I have found no evidence that it occurs naturally 
in halites or that this has been identified as any kind of environmental 
threat.

Sodium ferrocyanide becomes toxic because hydrogen cyanide gas is released 
by the addition of hot or concentrated acids.  Exposure to sunlight for any 
length of time will also release the toxic hydrogen cyanide gas.  Waste 
ferrocyanides in streams and lakes should not exceed 2 ppm because 
irradiated solutions become toxic to fish (Burdick and Lipscheutz C.A. 
44:10939f (1950)).  The bond between iron and the cyanide moeity is strong, 
giving ferrocyanides only a low order of toxicity.  When ferrocyanides are 
added to slightly acidic waters with iron salts present, Prussian blue 
(ferric ferrocyanide) will form.

That's about all I can tell you.

Cheers,

Mark.

Moderator's note: Here is another link from a chemical manufacturer that gives 
you some more information about  yellow prussiate.

Kieran


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