MadSci Network: Chemistry |
Hi Scott Nitrates: a nitrate is something containing a N03- ion, the systematic name is nitrate (V) (as N is in the +5 oxidation state). If I told you every nitrate compound this message would be very long, but they act as most anions do. The nitrate ion is quite large and so expect covalent character with M+ ions of high charge density, eg LiNO3. Apart from LiNO3, all Gp I and II nitrates decompose under heat: 2MNO3 ---> 2MNO2 + O2 (for GpI) 2M(NO3)2 ---> 2MO + 4NO2 + O2 Nitrates have been used for things such as: If you have studied electrochemical cells, you will have found saturated KNO3 used in salt bridges. Back in the day, silver nitrate (AgNO3) was used to develop photographs as it will react with halogen ions (Br- or I- usually) in light. Fertilisers such as Ammonium nitrate, NH4NO3 and Nitrophos, Ca(H2PO4)2 + Ca(NO3)2. Nitric acid, HNO3, a reasonably strong acid as NO3- dissociates easily in solution and is large - making it a good proton donor. This is made by adding H2SO4 (conc.) to nitrate salt... which is used in the preparation of TNT. I probably shouldn't tell you that, but some people do chemistry to make explosions. The common test for the NO3- ion is the "Brown Ring Test. Add Fe2+(aq) to nitrate solution and then add H2SO4 carefully. The solutions stay in separate layers and a brown ring should appear between the solutions, caused by the [(Fe(H2O)5 NO]2+ ion. Strictly speaking, nitrates come from stars as thats where all the Oxygen and Nitrogen comes from. I hope that answers your question Paul Henderson
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