MadSci Network: Chemistry |
When an aluminum object is anodized, it is placed in an acid bath and subjected to DC current which causes a layer of aluminum oxide to build up on its surface. Immediately after being anodized, the pores of the aluminum oxide are open so that various dyes or other chemicals can be deposited into the pores to produce different colors. The object is then submerged into boiling water which hydrates the aluminum oxide coating, causing it to swell and close the pores. This anodized layer protects the rather soft and chemically reactive aluminum from scratches and corrosion. The aluminum oxide layer can be removed with sodium hydroxide or other base, leaving a bare aluminum surface. Since oven cleaner is often mostly sodium hydroxide, it can chemically remove the anodized layer. Since only the aluminum and aluminum oxide are removed by sodium hydroxide, any alloying agents in the aluminum, as well as any metals deposited as part of the gold color are left behind as "smut." Most anodizing shops use a large tank of sodium hydroxide solution to evenly remove the anodized layer. The smut is then removed by another tank of solution. A serious hazard is presented by the sodium hydroxide, either as a solution or as a dry material. If it spills on the skin, there is no sensation that it is there; only a slippery feeling to the skin as the skin is dissolved. Additionally, sodium hydroxide can cause permanent blindness if it gets into the eyes. Not the kind of material to mess around with without protective gear. After removing the anodized layer, the remaining aluminum is very soft and scratches very easily. It is difficult to polish, particularly if you wish to preserve details in the surface. I would recommend that you have your tray professionally stripped of the anodized layer and then perhaps have it electropolished. Many plating shops in larger cities also do anodizing and electropolishing. After electropolishing, a thin clear anodized layer would protect your tray from scratches. In my city, a plating shop will do the job for its minimum job cost of about $35. In my mind, its money well spent.
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