MadSci Network: Earth Sciences |
Ryan, I am not an expert on icebergs, but I do know a little about claims for pure water. While it is true, snow that fell thousands of years ago are free of practically all human conatmination (especially for the snow that fell on Antarctica), snow or precipitation of any kind for that matter, is not chemically pure. First, small droplets of water or ice crystals that form in the upper atmosphere form around a nucleus. That means that there must be a dust particle for the water to begin condensing around. This dust particle may have been a microcrystal of salt placed in the atmosphere when waves sent spray into the air. It may be a particle of ash from a forest fire or from a volcanic eruption. The water cycle has been in operation for billions of years and precipitation has been interacting with atmospheric particulates and compounds for all that time. For instance, all rain is acid rain. Always has been, always will be. The atmosphere contains aproximately 350 ppm CO2. The meteorological information has demonstrated a steady rise in the background CO2 since the industrial revolution started in the 1850's from 280 ppm, but a good sized volcanic eruption can place millions of tons of the gas into the atmosphere in a shrot period of time. When rain falls from the sky, some of the CO2 naturally dissolves in the rain drops, making carbonic acid rain with a pH as low as 5.5 (Neutral is 7.0). Higher CO2 concentrations lower the pH to the 4.3 to 4.5 range. This excessively low pH is referred to as industrial acid rain. I have collected rain from all over the United States (including Hawaii) and have measured the electrical conductivity. This is a measure of the charge-carrying ions dissolved in the rain and can be used as an indication of the purity of water. Everything else being equal, the closer one is to the sea, the higher the conductivity. The sea spray contributes significant amounts of salt to the rain. The farther inland, the lower the salt content. Chemically pure water has a conductivity of 0.055 uS/cm. Rain water samples are usually in the range of 4 to 10 uS/cm. For comparison, the City of Phoenix municipal water has an electrical conductivity of between 800 and 1,100 uS/cm. and distilled water you buy in the store is in the range of 3 to 5 uS/cm. from the dissolved carbon dioxide (CO2) dissolved in it. Some groundwater that passes over "green sand" has been naturally softened by ion exchange. This is similar to the processes used in your home water softener. Water from these aquifers was deposited underground thousands, tens of thousands or more years ago. Much of it is also free of human contamination. Withe the additional filtering and potential ion exchange, this is not a bad source for drinking water. Do I think melted glacier water is the purest on the Earth? Absolutely not. Any high school student could prepare better water with a distillation apparatus in a simple laboratory. Homeowners all over the world are making water that good under thier kitchen sinks. Do I think it is better than most of the municipal water sources available in the U.S.? Probably. You can get water as chemically pure by simply passing any municipal water through a carbon filter and a reverse osmosis unit. These devices remove up to 99% of everything dissolved in the water. That puts it into the good rainwater category, with much more control over the pesky trace chemicals left in it. The carbon filter will remove the organics and the chlorine. Some people point to the fact that glacier water makes very clear ice and cite this fact to support its purity. Ice primarily is cloudy from dissolved air in the water at the time it freezes. Snow that has formed glaciers has had time to exclude the dissolved air from it, thereby making crystal clear ice. Just boil the water before you freeze it for ice cubes and you can make crystal clear ice as well. If all of this sounds like too much human intervention and refining of the water, remember, the hydrologic cycle naturally sand filters, biologically modifies, and distills all of the water on the surface of the Earth in its process of purifying and recycling it. Chemists have simply standardized the final purification of the water. It can't be too bad, because it is this process of water purification that has stopped almost all of the waterborne epidemics that took place when people left water purification to nature alone. Melted glacier water sounds good but I think it is playing on the romantic side of people's good sense. Remember, some of the snow that makes up glaciers in Alaska and Canada could have easily come in contact with wooly mammoths or early migrating hunters. It never hurts to remember the adage, "Don't eat (or drink) yellow snow!" Other pollutants have been added by humans, but the Earth weather system does a good job adding some of its own. I hope this helps. Encyclopedia Britannica, Macropedia, Atmosphere
Try the links in the MadSci Library for more information on Earth Sciences.