MadSci Network: Physics
Query:

Re: How is gold tempered (hardened)

Date: Wed May 2 00:56:53 2001
Posted By: James Griepenburg, , Chemical consultant, Chemmet Services
Area of science: Physics
ID: 985468335.Ph
Message:

John,

That probably was a gold alloy dagger and a work of art.  All you want to 
know about gold can be found in the American Society for Metals  “Metals 
Handbook” 9th edition, volume 2.

Gold does work harden.  Annealed[300 C] wrought gold has a tensile of 130M 
Pa[mega pascals] and an elongation of 45%.  At 60% reduction the tensile 
increases to 220 M Pa and the elongation drops to 4%.  The hardness about 
doubles but it is still a soft metal.

To change the hardness, color, workability, corrosion resistance, cost, 
and other properties of gold, gold is alloyed with silver, copper, nickel, 
zinc, palladium, platinum, and probably other metals and in various 
combinations of the above.    There are many combinations: silver-copper 
mixes are most common for yellow gold, while nickel, zinc and palladium 
are found in white gold.  Platinum is used in some electrical alloys where 
hardness and superb corrosion resistance is needed. Some platinum gold 
alloys reach tensile over 900 M Pa.

Gold is sold by weight; 24 carat gold is pure gold.  Common carat weights 
are 22,18, 14, and 10.  18 carat gold is 75 % gold by weight but only 50-
60 atom % gold.  Its properties are still largely determined by the 
properties of gold.  The lower carat weights are less than 50 atomic % 
gold and the properties are very dependent on the alloying metals.  Many 
of the alloys respond to heat treating and tempering to vary hardness.  
The lower the gold content the more susceptible the alloy is to corrosion 
and the greater the color variations.

If you have a working interest in goldsmithing, which seems to be an 
interesting artisan’s field, I would suggest visiting a local working 
artist and ask some polite questions.  They would probably be all too 
happy to talk to someone with a genuine interest in the field and might 
have a specific answer.  Or the next time we are in Cairo....

Regards
JimG



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