MadSci Network: Physics
Query:

Re: What would be the 'normal' air pressurefor 25 C, 50 C, 75 C, and 90 C?

Date: Mon Feb 11 17:53:46 2002
Posted By: Jaime Valencia-Rodríguez, Guest Researcher, Chemical Science and Technology Lab, NIST.
Area of science: Physics
ID: 1011670357.Ph
Message:

Dear Jen:

Thank you very much for your question and your kind compliments.
In order to answer properly your question, I need to address some issues 
beforehand.

In the very nice site http://kids.earth.n
asa.gov/archive/air_pressure/ we 
found the following information:

Air pressure is the force exerted on you by the weight of tiny particles 
of air (air molecules). Although air molecules are invisible, they still 
have weight and take up space. Since there's a lot of "empty" space 
between air molecules, air can be compressed to fit in a smaller volume. 
When it's compressed, air is said to be "under high pressure". Air at sea 
level is what we're used to, in fact, we're so used to it that we forget 
we're actually feeling air pressure all the time! 
Weather forecasters measure air pressure with a barometer. Barometers are 
used to measure the current air pressure at a particular location 
in "inches of mercury" or in "millibars" (mb). A measurement of 29.92 
inches of mercury is equivalent to 1013.25 millibars. 
How much pressure are you under? Earth's atmosphere is pressing against 
each square inch of you with a force of 1 kilogram per square centimeter 
(14.7 pounds per square inch). The force on 1,000 square centimeters (a 
little larger than a square foot) is about a ton! 
Why doesn't all that pressure squash me? Remember that you have air inside 
your body too, that air balances out the pressure outside so you stay nice 
and firm and not squishy. 
Air pressure can tell us about what kind of weather to expect as well. If 
a high pressure system is on its way, often you can expect cooler 
temperatures and clear skies. If a low pressure system is coming, then 
look for warmer weather, storms and rain. 

The Mercurial Barometer: Measuring Pressure
Based on a principle developed by Evangelista Torricelli in 1643, the 
Mercurial Barometer is an instrument used for measuring the change in 
atmospheric pressure. It uses a long glass tube, open at one end and 
closed at the other. Air pressure is measured by observing the height of 
the column of mercury in the tube. At sea level, air pressure will push on 
the mercury at the open end and support a column of mercury about 30 
inches high. If you used water instead of mercury, you would need a glass 
tube over 30 feet in length. 
As atmospheric pressure increases, the mercury is forced from the 
reservoir by the increasing air pressure and the column of mercury rises; 
when the atmospheric pressure decreases, the mercury flows back into the 
reservoir and the column of mercury is lowered. 

The site has a virtual barometer, and the following instructions for 
making your own barometer:

Make Your Own Barometer
Materials Needed:
Drinking straw (clear plastic). 
Narrow-neck glass bottle. 
A rubber or cork stopper which fits in the neck of the bottle 
Instructions
Insert a drinking straw into the bottle. 
Fill the bottle about half-way full of water. 
Seal the neck of the bottle around the straw either with the rubber 
stopper or a cork. 
Make sure the end of the straw is immersed in the water and that the water 
level in the straw is above the top of the bottle. 
As the air pressure outside the bottle decreases, the trapped air inside 
the bottle will push the water up the straw. As the air pressure outside 
the bottle increases, it will push the water farther down the straw. 
Please Note: You'll need to keep your barometer's temperature constant, 
since temperature will also affect the water level.


What Happens if Air Pressure Changes? 
Why do my ears pop? If you've ever been to the top of a tall mountain, you 
may have noticed that your ears pop and you need to breathe more often 
than when you're at sea level. As the number of molecules of air around 
you decreases, the air pressure decreases. This causes your ears to pop in 
order to balance the pressure between the outside and inside of your ear. 
Since you are breathing fewer molecules of oxygen, you need to breathe 
faster to bring the few molecules there are into your lungs to make up for 
the deficit. 
As you climb higher, air temperature decreases. Typically, air 
temperatures decrease about 3.6° F per 1,000 feet of elevation. 

Now, in another interesting place  http://www.usatoday.com
/weather/wstdatmo.htm we learn that:

The standard atmosphere 
The standard atmosphere can be thought of as the average pressure, 
temperature and air density for various altitudes. It is useful for 
engineering calculations for aircraft. It also shows in a general way the 
pressures and temperatures to be expected at various altitudes. The 
standard atmosphere is based on mathematical formulas that reduce 
temperature and pressure by certain amounts as altitude is gained. But, 
the results are close to averages of balloon and airplane measurements at 
various altitudes. 
The table below uses metric units, which scientists use

Height 	Temperature	   Pressure	  Density
(m)	    (C)	             (hPa)        (kg/m3)
0000            15.0         1013           1.2
1000             8.5          900           1.1
2000             2.0          800           1.0
3000            -4.5          700           0.91
4000           -11.0          620           0.82
5000           -17.5          540           0.74
6000           -24.0          470           0.66
7000           -30.5          410           0.59
8000           -37.0          360           0.53
9000           -43.5          310           0.47
10000          -50.0          260           0.41
11000          -56.5          230           0.36
12000          -56.5          190           0.31
13000          -56.5          170           0.27
14000          -56.5          140           0.23 
15000          -56.5          120           0.19
16000          -56.5          100           0.17
17000          -56.5           90           0.14
18000          -56.5           75           0.12
19000          -56.5           65           0.10
20000          -56.5           55           0.088
21000          -55.5           47           0.075
22000          -54.5           40           0.064
23000          -53.5           34           0.054
24000          -52.5           29           0.046
25000          -51.5           25           0.039
26000          -50.5           22           0.034
27000          -49.5           18           0.029

Source: Aerodynamics for Naval Aviators 
Note: This is a summary table. For a more detailed table or a table in 
metric units, consult an aerodynamics textbook. Many weather textbooks 
also have tables of the standard atmosphere. 


Finally in the very didactic site  http://
www.met.tamu.edu/class/Metr151/tut/pres/hydroequ.html we will find 
the answer to your question. But first we need to consider an equation:


We'll start with a mathematical representation of the vertical balance of 
forces and then construct the equation from the following two statements: 

Force equals mass times acceleration 
The gravitational force equals the vertical pressure gradient force. 

	Recall that the vertical pressure gradient force is a result of 
air pressure, which pushes in all directions. A vertical pressure gradient 
represents a situation in which the pressure decreases with height, so 
that the air pressure pushing upward on the bottom of a parcel of air is 
larger than the air pressure pushing downward on the top of the parcel of 
air. The force per unit volume is just the rate of change of pressure with 
height. Mathematically, that is written as dp/dz, where p is pressure, z 
is height, and the entire expression represents the change in pressure 
over a tiny vertical distance divided by the length of that distance. 
The gravitational force is usually expressed mathematically in a very 
simple way, by writing it as the mass of the object times the acceleration 
gravity causes. This acceleration is a constant, equal to 9.8 m/s2. 
(Sooner or later, you'll need to memorize this number). To compare to 
pressure, we need the force per unit volume: m g / V or g, where m is the 
mass of a volume of air, g is the gravitational acceleration, V is the 
size of the volume, and , which is m / V, is the density of air. 
So the mathematical statement that gravity is balanced in the atmosphere 
by the vertical pressure gradient force is: 

dp/dz = - g 

The minus sign is there because the force of gravity is oriented 
downwards, in the negative z direction. This mathematical statement is 
called the "hydrostatic equation", and the balance of forces it represents 
is called "hydrostatic balance". 
We'll start with the simplest interpretation: since the right-hand side of 
the equation is always negative (g is a constant, and there's no such 
thing as negative density), the left-hand side must always be negative, 
too. Recall the definition of dp/dz: the change in pressure over a tiny 
vertical distance divided by the length of that distance. This change (or 
any derivative, for that matter) must always be measured in the direction 
in which z (or whatever variable is in the denominator) increases. So if 
dp/dz is to be negative, p must decrease as z increases. All of this is 
just a fancy way of saying that the higher you go, the smaller the 
pressure. But you probably knew that by now. 
Second, you may remember from high school physics that weight is mass 
times the acceleration of gravity. So g turns out to be the weight of air 
per unit volume. Thus, the hydrostatic equation states that the vertical 
change in air pressure is equal to the weight of the air. 
Imagine a layer of air 100 m thick. According to the hydrostatic equation, 
if we know the average weight or mass of the air per unit volume, we can 
calculate the change in air pressure between the top and the bottom. 
A typical value for the density of air near sea level is 1.3 kilograms per 
cubic meter. (To me, that's surprisingly heavy!) With that number, you 
have everything you need to know to compute the change in air pressure 
over 100m using the hydrostatic equation. 
From the preceding section, you may realize that the density of the air 
has a big effect on pressure. In a sense, the air pressure at a given 
level of the atmosphere is equal to the average density of all the air 
above that level. The denser the air, the more rapidly pressure increases 
as you go downward in the atmosphere. Careful, though: this does not mean 
that dense air implies high pressure. It means that dense air corresponds 
to a rapid change of pressure with height. 
I like to draw an analogy to stacking boxes. Suppose each box is equally 
filled with (brown) popcorn, so that each box weighs the same. Suppose you 
stack three boxes. The weight at the bottom of the stack is equal to the 
total weight of the three boxes, while the weight two-thirds of the way up 
is equal to the weight of just one box. 
Just like weight increases downward, so pressure increases downward. And 
the amount by which pressure or weight change over a given vertical 
distance depends directly on the density of the intervening layers
The same principle applies to the atmosphere. Imagine two regions of the 
atmosphere, one with dense air on top of light air, and one with light air 
on top of dense air. The pressure at the ground at these two places might 
very well be equal, if there's the same total amount of air above them. 
Well, the atmosphere is like that: Near the ground, the air is warmer and 
less dense near the equator than near the pole, while at a height of 15 to 
20 km, the air is actually warmer and less dense near the pole than near 
the equator. The surface pressures at the equator and pole are almost 
identical. 
If you think about it, it should be obvious that the lower you are in the 
atmosphere, the more air you have above you, and therefore the higher the 
air pressure. Indeed, the change in pressure with height is so regular 
that meteorologists use pressure as a vertical coordinate instead of 
height. So instead of seeing weather maps at, say, 1.5 km, you would see a 
map at 850 mb, which is approximately 1.5 km above sea level. 
Since pressure and density are so closely related, you might expect that 
temperature is closely related to pressure too. It is. The three 
quantities are tied together through the ideal gas law. You are probably 
familiar with the ideal gas law in the following form: pV = nRT (pressure 
times volume equals the number of molecules times the gas constant times 
temperature). Through a little bit of mathematical manipulation which I 
won't go into here, you can convert the terms involving volume and number 
of molecules into an expression involving density: 

p = R* T 

Now R* is a constant. Imagine two air parcels at the same pressure (side 
by side). Suppose that parcel 1 is warmer than parcel 2. Since the ideal 
gas law must be satisfied for both air parcels, and the pressure is the 
same for each of them, the right-hand side of the equation must be the 
same for each of them, too. Since R* is constant, if one has a higher 
density, it must also have a lower temperature, and vice versa. 

In order to determine the "normal" temperature, you need to know 
the "normal" pressure.

I hope this help


Regards


Jaime Valencia



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