MadSci Network: Science History |
Aluminium is the most common metallic element in the earth's crust! There is even more aluminium than iron. But aluminium is also a metal that is extraordinarily difficult to separate from its compounds. The name aluminium comes from "alum", which is potassium aluminium sulfate, a compound of aluminium. It was used by the ancient Greeks and Romans as a medicine. Corundum, and sapphire, and several other gemstones, are entirely or largely made of aluminium oxide. They have also been known for a very long time. In England in the early 1800s, Humphry Davy was able to prepare a number of elements that had been difficult to separate from their compounds -- sodium and potassium in 1807, and magnesium and calcium in 1808. He used electrolysis of molten alkalis for the first two, or powdered oxides mixed with mercury for the others. He tried hard to prepare aluminium metal in this way as well, but failed. The metal was first prepared in Denmark, by the scientist Oersted. He reacted aluminium chloride with potassium metal dissolved in mercury in 1825. The metal he prepared was rather impure. The first reasonably pure aluminium was prepared in 1827 using a refinement of Oersted's method. The scientist was Woehler, and the location was Germany. My references are 'CRC Handbook of Chemistry & Physics', page B-6, and 'Chemistry of the Elements', Greenwood & Earnshaw, pages 75, 118, and 243. There are many web-based periodic table sites that give this information. Here is one web page about aluminium.
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