MadSci Network: Environment & Ecology
Query:

Re: 3% CO2 remains in H2O as carbonic acid; rest 97% in a closed vessels?

Date: Fri Aug 11 13:16:19 2006
Posted By: Dan Berger, Faculty Chemistry/Science, Bluffton University
Area of science: Environment & Ecology
ID: 1155187337.En
Message:

CO2 as green house gas is a serious problem. I read an article by Mr. Dan 
Berger, Faculty Chemistry/Science, Bluffton College, ID: 892859430.Ch
that  "---only about 3% of dissolved CO2 will remain in water in the form of 
carbonic acid". 
So, I was trying to understand, if CO2 passed through water in a closed
vessel, 
(1)how much CO2 will get absorbed and how long it remains in water and 
(2)what happens to the rest 97%  CO2 if the vessel is closed one.

Part of your problem is that you seem to have misunderstood my original answer, so I will try to summarize the points from it, that address your question:

  • Carbon dioxide has a relatively low solubility -- a saturated solution at 25°C is about 0.03 moles/liter -- so not very much of it will dissolve in water.
  • Of the CO2 that is dissolved, only about 3% will be in the form of carbonic acid. That doesn't mean that the other 97% escapes! It's still in solution. The statement that dissolved CO2 is in the form of carbonic acid is a gross exaggeration.

If you're passing CO2 through water in a closed vessel, it will only dissolve to the extent of 0.03 moles per liter at "standard temperature and pressure." But... if the vessel is closed the gas can't escape. So it just stays there, either as gas above the liquid or as a super-saturated solution (since you're pushing the solubility equilibrium toward more dissolved gas by increasing the pressure of gas above the liquid).

Carbonated beverages get super-saturated with CO2 because they are pressurized with pure carbon dioxide when they are sealed. When the pressure is released, you often see the gas bubbling out of solution (which is why soda pop or carbonated mineral water fizzes on opening).

But again, the question of dissolved CO2 forming carbonic acid (only 3% of it does) is entirely separate from the question of an overpressure of CO2 above a saturated solution of the gas.

I hope this was helpful.

Dan Berger


Current Queue | Current Queue for Environment & Ecology | Environment & Ecology archives

Try the links in the MadSci Library for more information on Environment & Ecology.



MadSci Home | Information | Search | Random Knowledge Generator | MadSci Archives | Mad Library | MAD Labs | MAD FAQs | Ask a ? | Join Us! | Help Support MadSci


MadSci Network, webadmin@madsci.org
© 1995-2006. All rights reserved.