MadSci Network: Physics |
The way you have asked your question provides the key to the answer. Heat transfer from warm air circulating around a glass is different from heat transfer (and mass transfer) by condensation of a liquid on the outside of a glass. Generally there are three ways to transfer heat; conduction, convection, and radiation. For heat to be transferred by conduction, two solid surfaces must be in physical contact with each other. In the case of your question, heat is transferred through the bottom of your glass by conduction. Since metal is a better conductor than wood, cloth, or plastic, your ice will tend to melt faster when sitting on a metal table than if it is sitting on a wood or other surface with poorer thermal conductivity. Radiation is another way that heat is transferred. Hot objects (like the sun) transfer heat by radiation or heat rays. The hotter the source (and the cooler the object exposed to the radiation), the more heat is transferred. So, keeping a glass out of direct sunlight will also make your ice last longer. Convective heat transfer depends upon the movement of fluid (in this case air) around an object . As air comes into contact with the cold glass surface, the air temperature decreases, and the glass temperature increases. Ice within the glass will then melt to cool down the glass. The rate of heat transfer depends upon the heat capacity of the air, the amount of surface exposed, the speed of the air, and the temperature difference between the air and the glass. If there is wind, more air moves around the glass, and more heat is transferred (melting more ice). On a humid day, water vapor in the air will condense on the glass, forming liquid droplets. In this case, heat transfer is helped by mass transfer; you are removing water vapor out of the air and depositing it on your glass as liquid. In order to change from gas to liquid, the water vapor in the air must give up energy; exactly the same amount of energy that it took to vaporize the water in the first place. The heat of vaporization of liquid water is about 540 calories per gram. When ice melts, energy has to be adsorbed to change the ice from solid to liquid. This heat of fusion is about 80 calories per gram. So, almost 7 times as much heat is required to vaporize water than to change ice to liquid. So, if you collect one teaspoon of moisture on the outside of your glass, you have melted about 7 teaspoons of ice inside the glass. Another way to analyze your question is to look at it in reverse. Let's say that the next time before you take a shower, you stand in a room, just to see how fast you cool off. Then, after taking a shower, you stand in the same room dripping wet. As the water evaporates away from your skin, it will cool you much more rapidly than before you get all wet. On a humid day, water will evaporate more slowly. On a dry day, the water will evaporate more quickly (because there is less water already in the air). A dry hot day is generally more comfortable than a wet hot day, since perspiration can dry more quickly in a dry environment. It is also the reason that dehumidification is an important consideration when purchasing an air conditioner. You can find a useful discussion on heat transfer and the latent heat of evaporation here: http://okfirst.ocs.ou.edu/train/meteorology/HeatTransfer.html Thanks for an interesting question.
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